Stannylene, diphenyl-

Base Information

• Chemical Name: Stannylene, diphenyl-
• CAS No.: 6381-06-2
• Molecular Formula: C12H10 Sn
• Molecular Weight: 272.921
• Mol file: 6381-06-2.mol

Synonyms:Tin,diphenyl- (6CI,7CI,8CI); Diphenylstannylene; Diphenyltin; NSC 162819

Chemical Property of Stannylene, diphenyl-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannylene, diphenyl-

There total 7 articles about Stannylene, diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyltin (1011-95-6) → dodecaphenylcyclohexastannane + diphenylstannane (6381-06-2)

Guidance literature:

With catalyst: (C₂H₅)2NH or morpholine or (CH₃)2SO; In not given;

DOI:10.1021/jo01064a025

Reference yield:

diphenyltin (1011-95-6) → diphenylstannane (6381-06-2)

Guidance literature:

In neat (no solvent); easy decomposition;;

DOI:10.1021/ja01415a026

Reference yield:

diphenyltin(IV) dichloride (1135-99-5) → diphenylstannane (6381-06-2)

Guidance literature:

With Na; In tetrahydrofuran; ammonia; byproducts: NaCl; NH3 (liquid); Ph2SnCl2 soln. (THF) added dropwise to soln. of Na (2 equiv.) (liq. NH3)at 200 K at stirring (in the dark); NH3 removed in N2 flow by warming to room temp., THF evapd. at room temp. in vac., residue dissolved in CH2Cl2, ppt. filtered off, solvent evapd., residue dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2011.05.001

upstream raw materials:

diphenyltin

tert-butyl alcohol-d

diphenyltin(IV) dichloride

Downstream raw materials:

tetraphenyltin(IV)

triphenyl methyl tin

trimethyl(phenyl)stannane

dimethyldiphenyltin

Refernces

• 1、 Bhattacharyya, Koyel X.,Akana, Jennifer A.,Laitar, David S.,Berlin, Jacob M.,Sadighi, Joseph P.. "Carbon-carbon bond formation on reaction of a copper(I) stannyl complex with carbon dioxide". . p. 2682 - 2684. Retrieved 2008.
• 2、 Bullock, John P.,Palazzotto, Michael C.,Mann, Kent R.. "Electrochemistry and infrared spectroelectrochemistry of MnSnPh4-n (M = CpMo(CO)3, Mn(CO)5, CpFe(CO)2; n = 1, 2)". . p. 4413 - 4421. Retrieved 2008/10/08.