cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato

Base Information

• Chemical Name: cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato
• CAS No.: 72282-44-1
• Molecular Formula: C₄₄H₂₈CoN₄O₁₂S₄
• Molecular Weight: 991.983
• Mol file: 72282-44-1.mol

Synonyms:cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato

Chemical Property of cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato

There total 2 articles about cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C46H33CoN4O12S4 → cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato (72282-44-1) + ethene (74-85-1)

Guidance literature:

In aq. phosphate buffer; at 25 ℃; pH=7; Photolysis; Inert atmosphere;

DOI:10.1002/ejic.201600208

Reference yield:

cobalt(II) diacetate tetrahydrate (6147-53-1) + 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (35218-75-8) → cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato (72282-44-1)

Guidance literature:

In N,N-dimethyl-formamide; Reflux;

DOI:10.1149/2.0481809jes

Reference yield:

cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato (72282-44-1) → cobalt(I) tetrakis(4-sulfonatophenyl)porphyrin (85028-59-7)

Guidance literature:

In water; other Radiation; (N2); pulse radiolysis of Co complex by γ-irradn. ((60)Co, 4 krd/min) at 21.+-.1°C in presence of i-PrOH or HCO2(1-) as radical scavengers; not isolated, detected by UV; Kinetics;

DOI:10.1021/j100232a011

upstream raw materials:

cobalt(II) diacetate tetrahydrate

5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin

Downstream raw materials:

{Co(NC₄H₂C(C₆H₄SO₃H))4CH(CH₃)2}

{Co(NC₄H₂C(C₆H₄SO₃H))4CH₃}

cobalt(I) tetrakis(4-sulfonatophenyl)porphyrin

Refernces

• 1、 Imabeppu, Kohei,Kuwano, Hiroyuki,Yutani, Eriko,Kitagishi, Hiroaki,Kano, Koji. "Photoinduced Homolysis of Alkyl-Cobalt(III) Bonds in a Cyclodextrin Cage". supporting information. p. 1784 - 1789. Retrieved 2016/05/02.