TPPS

Base Information

• Chemical Name: TPPS
• CAS No.: 35218-75-8
• Molecular Formula: C44H30 N4 O12 S4
• Molecular Weight: 935.006
• Mol file: 35218-75-8.mol

Synonyms:5,10,15,20-Tetra(p-sulfonatophenyl)porphyrin;5,10,15,20-Tetra(sulfophenyl)porphyrin;5,10,15,20-Tetrakis(4-sulfonatophenyl)porphine;5,10,15,20-Tetrakis(4-sulfonatophenyl)porphyrin;5,10,15,20-Tetrakis(4-sulfophenyl)porphine;5,10,15,20-Tetrakis(4-sulfophenyl)porphyrin;5,10,15,20-Tetrakis(sulfophenyl)porphyrin; NSC 177391; TPPS; TPPS(photoreactant); TPPS4; Tetrakis(4-sulfonatophenyl)porphine(2-); WR 247188;meso-Tetra(4-sulfonatophenyl)porphyrin; meso-Tetra(4-sulfophenyl)porphyrin;meso-Tetrakis(4-sulfonatophenyl)porphine;meso-Tetrakis(4-sulfonatophenyl)porphyrin; meso-Tetrakis(4-sulfophenyl)porphine;meso-Tetrakis(4-sulfophenyl)porphyrin;meso-Tetrakis(p-sulfonatophenyl)porphine;meso-Tetrakis(p-sulfonatophenyl)porphyrin;meso-Tetrakis(p-sulfophenyl)porphine; meso-Tetrakis(p-sulfophenyl)porphyrin; a,b,g,d-Tetrakis(4-sulfophenyl)porphine

Chemical Property of TPPS

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 307.30000
• Density: 1.607g/cm³
• LogP: 8.17620
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99.0% ^*data from raw suppliers

TPPS Hydrate(=Tetraphenylporphyrin Tetrasulfonic Acid Hydrate)[Ultra-high sensitive spectrophotometric reagent for transition metals] >85.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: TPPS is used in the process of electrostatic layer-by-layer adsorption process for formation of dye-polyelectrolyte organized molecular assemblies, and is used as a standard method to calibrate sonochemical efficiency of an individual reaction system.

Technology Process of TPPS

There total 8 articles about TPPS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin (35218-75-8)

Guidance literature:

5,15,10,20-tetraphenylporphyrin; With sulfuric acid; at 100 ℃; for 8h;

With sodium hydroxide; In water; pH=9;

DOI:10.1016/j.ica.2020.119929

Reference yield: 90.0%

5,10,15,20‐tetrakis(4‐chlorosulphonylphenyl)porphyrin → 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (35218-75-8)

Guidance literature:

With water; for 12h; Heating;

Reference yield: 88.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (35218-75-8)

Guidance literature:

With sulfuric acid; for 6h; Heating;

DOI:10.1039/b904199k

upstream raw materials:

tetra(4-fluorosulfonylphenyl)porphin

5,15,10,20-tetraphenylporphyrin

benzaldehyde

pyrrole

Downstream raw materials:

tetrakis(sulphonatophenyl)porphyrin

tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)

cobalt(II) meso-5,10,15,20-(tetraphenyl-4-sulfonato)porphyrinato

Refernces

• 1、 Srivastava,Tsutsui. "". . p. 2103. Retrieved 1973.
• 2、 Busby et al.. "". . p. 1554. Retrieved 1975.
• 3、 Meng,James,Skov,Korbelik. "Porphyrin chemistry pertaining to the design of anti-cancer drugs; part 2. The synthesis and in vitro tests of water-soluble porphyrins containing, in the meso positions, the functional groups: 4-methylpyridinium, or 4-sulfonatophenyl, in combination with phenyl, 4-pyridyl, 4-nitrophenyl, or 4-aminophenyl". . p. 2447 - 2457. Retrieved 1994.
• 4、 Esfandiari bayat, Zahra,Rahiminezhad, Hajar,Zakavi, Saeed. "Solvent effects on catalytic activity of manganese porphyrins with cationic, anionic and uncharged meso substituents: Indirect evidence on the nature of active oxidant species". . . Retrieved 2018/11/23.