Iron dodecacarbonyl, stabilised with 5-10% methanol, 95%

Base Information

• Chemical Name: Iron dodecacarbonyl, stabilised with 5-10% methanol, 95%
• CAS No.: 100447-70-9
• Molecular Formula: C12Fe3 O12
• Molecular Weight: 503.666
• Mol file: 100447-70-9.mol

Synonyms:Iron dodecacarbonyl, stabilised with 5-10% methanol, 95%

Chemical Property of Iron dodecacarbonyl, stabilised with 5-10% methanol, 95%

Chemical Property:

• PSA: 204.84000
• LogP: 5.40950

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron dodecacarbonyl, stabilised with 5-10% methanol, 95%

There total 17 articles about Iron dodecacarbonyl, stabilised with 5-10% methanol, 95% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + hex-3-yne (928-49-4) → Co2*6CO*C2H5CCC2H5=Co2(CO)6C2H5CCC2H5 (41626-27-1) + FeCo(1+)*6(CO)*C2H5CCCHCH3(1-)=FeCo(CO)6C2H5CCCHCH3 (78109-42-9) + triiron dodecacarbonyl (100447-70-9)

Guidance literature:

In acetone; refluxed in acetone for 5 h under N2 atmosphere, filtration of excess Fe(CO)5 solvent removed in vac., further products; dissolved in chloroform and chromd. on silica gel, eluent petroleum ether and chloroform, elem. anal.;

DOI:10.1021/ic00132a007

Reference yield: 69.6%

diiron nonacarbonyl (15321-51-4) + Os2(CO)6(μ-I)2 → dodecacarbonyl triosmium (15696-40-9) + (μ-H)Os3(CO)10(μ-I) + [FeOs2(CO)12] (12560-38-2) + Os2Fe(CO)10(μ-I)2 (198145-46-9) + triiron dodecacarbonyl (100447-70-9)

Guidance literature:

In benzene; Ar-atmosphere; stirring Os-complex with excess of Fe-complex (room temp., 2 h), refluxing for 10 h; filtration, evapn., chromy. (SiO2, hexane);

DOI:10.1016/S0022-328X(96)06957-4

Reference yield: 61.0%

[NEt3H][HFe3(CO)11] → triiron dodecacarbonyl (100447-70-9)

Guidance literature:

With hydrogenchloride; In methanol; water; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c7dt01506b

upstream raw materials:

iron pentacarbonyl

Co₂*6(CO)*C₂H₅CCCHOHCH₃=Co₂(CO)6C₂H₅CCCHOHCH₃

dicobalt octacarbonyl

hex-3-yne

Downstream raw materials:

Fe(CO)4(CH₃C₆H₄NC)

[Fe2(CO)6(μ,μ'-(p-MeC6H4N)2CN-p-MeC6H4)]*0.5hexane

Fe(CO)3(CNC₆H₁₁)2

Fe(CO)4(CNC₆H₁₁)

Refernces

• 1、 Femoni, Cristina,Iapalucci, Maria Carmela,Longoni, Giuliano,Zacchini, Stefano,Zazzaroni, Enrico. "Synthesis and X-ray structure of the [{Fe3(CO)9( 3-O)}2H]3- trianion: Dimerization of a metal carbonyl cluster via formation of an exceptionally short hydrogen bond". . p. 2644 - 2651. Retrieved 2007.
• 2、 Liu, Xiao-Ming,Hu, Shan-Fang,Zeng, Guang,Shi, Zhan,Zhu, Lei. "Structural Interconversion of Bimetallic Carbonyl Clusters Induced by a NHC Ligand and Its Selectivity on Fragments". . p. 1983 - 1986. Retrieved 2014/12/09.