TERBIUM(III) CHLORIDE HYDRATE

Base Information

• Chemical Name: TERBIUM(III) CHLORIDE HYDRATE
• CAS No.: 19423-82-6
• Molecular Formula: Cl₃Tb*2H₂O
• Molecular Weight: 301.315
• UNII: IO29D13DLW
• DSSTox Substance ID: DTXSID0047117
• Nikkaji Number: J134.244D
• Wikipedia: Ytterbium(III)_chloride
• Mol file: 19423-82-6.mol

Synonyms:TERBIUM(III) CHLORIDE HYDRATE;TERBIUM (III) CHLORIDE, HYDROUS;TERBIUM(III) CHLORIDE HYDRATE, 99.99%

Chemical Property of TERBIUM(III) CHLORIDE HYDRATE

Chemical Property:

• Melting Point: 145-149 °C(lit.)
• PSA: 9.23000
• LogP: 2.00420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 278.845426
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Terbium Chloride 99.99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Yb+3]

Technology Process of TERBIUM(III) CHLORIDE HYDRATE

There total 17 articles about TERBIUM(III) CHLORIDE HYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III, IV) oxide + water (7732-18-5) → TbCl3*5H2O (13798-24-8,19423-82-6)

Guidance literature:

In hydrogenchloride; Tb4O7 was heated with concd. aq. HCl; soln. was evapd. to dryness in vacuo at 50°C;

DOI:10.1016/j.ica.2003.11.011

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III, IV) oxide → terbium(III) chloride hexahydrate (13798-24-8,19423-82-6)

Guidance literature:

With dihydrogen peroxide; In hydrogenchloride; oxide dissoln. (H2O2 continuously addn. during dissoln.), water boiling off (stirring), pptn. until thick slurry obtained, slurry cooling to room temp.; solid filtration off, vac. treating at 40°C (grinding, stirring);

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III) oxide + water (7732-18-5) → terbium(III) chloride hexahydrate (13798-24-8,19423-82-6)

Guidance literature:

In hydrogenchloride; lanthanide oxide dissolved in dilute HCl; dried;

DOI:10.1016/S0022-2860(02)00614-2

upstream raw materials:

hydrogenchloride

water

dihydrogen peroxide

terbium(III) chloride hexahydrate

Downstream raw materials:

(TbCl₂(((H₃C)2N)3PO)4)⁽¹⁺⁾*B(C₆H₅)4^(1-)=(TbCl₂(((H₃C)2N)3PO)4)(B(C₆H₅)4)

Refernces

• 1、 Xu, Xiao-Yu,Yan, Bing. "Intercalation of lanthanide cations to a layer-like metal-organic framework for color tunable white light emission". . p. 1178 - 1185. Retrieved 2015/02/02.
• 2、 Lyszczek,Iwan. "Investigation of desolvation process in lanthanide dinicotinates". . p. 633 - 639. Retrieved 2011/04/22.