Technology Process of 5.6-μ-(AuPCy3)-nido-B10H13
There total 6 articles about 5.6-μ-(AuPCy3)-nido-B10H13 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
dichloromethane;
to a stirred soln. of Au-complex in CH2Cl2 was added dropwise a soln. of B10H14 in CH2Cl2, the solid was filtered off, washed with ice-cold CH2Cl2, the vol. of filtrate was reduced in vac. and cooled to -30°C (second crop); recrystd. from CH2Cl2; elem. anal.;
DOI:10.1039/DT9870002761
- Guidance literature:
-
In
dichloromethane;
to a stirred soln. of (NEt3H)B10H13 in CH2Cl2 was added dropwise Au-complex in CH2Cl2, the soln. was stirred for ca 4 h at ambient temp.; the solvent was removed in vac., CH2Cl2 was added (pptn.); elem. anal.;
DOI:10.1039/DT9870002761
- Guidance literature:
-
With
CF3CO2H;
In
dichloromethane;
under N2, addn. of CF3CO2H soln. to stirred soln. of borane, color change to pale yellow; prompt removal of solvent in vac., (31)P-NMR detn.;
