1,1,3,3-Tetrachloroprop-1-ene

Base Information

• Chemical Name: 1,1,3,3-Tetrachloroprop-1-ene
• CAS No.: 18611-43-3
• Molecular Formula: C3H2 Cl4
• Molecular Weight: 179.861
• Hs Code.: 2903299090
• European Community (EC) Number: 675-808-5
• DSSTox Substance ID: DTXSID90415967
• Nikkaji Number: J1.424.390I
• Mol file: 18611-43-3.mol

Synonyms:1,1,3,3-tetrachloroprop-1-ene;18611-43-3;1,1,3,3-tetrachloropropene;1,1,3,3-tetrachloro-1-propene;SCHEMBL151237;DTXSID90415967;1-Propene, 1,1,3,3-tetrachloro-;AKOS006230285;FT-0605997;InChI=1/C3H2Cl4/c4-2(5)1-3(6)7/h1-2

Chemical Property of 1,1,3,3-Tetrachloroprop-1-ene

Chemical Property:

• Vapor Pressure: 1.49mmHg at 25°C
• Refractive Index: 1.511
• Boiling Point: 176.1°C at 760 mmHg
• Flash Point: 64°C
• PSA: 0.00000
• Density: 1.532g/cm³
• LogP: 3.10910
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 179.888111
• Heavy Atom Count: 7
• Complexity: 71

Purity/Quality:

99.9% ^*data from raw suppliers

1,1,3,3-Tetrachloroprop-1-ene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.; R36:Irritating to eyes.
• Hazard Codes: R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.; R36:Irritating to eyes.
• Statements: R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.; R36:Irritating to eyes.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36/37/39:Wear suitabl

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(Cl)Cl)C(Cl)Cl

Technology Process of 1,1,3,3-Tetrachloroprop-1-ene

There total 21 articles about 1,1,3,3-Tetrachloroprop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.1%

1,1,3-trichloro-3,3-difluoropropane (460-63-9) → (Z)-1-chloro-3,3,3-trifluoro-1-propene (99728-16-2) + 1,1,3,3-tetrachloro-1-propene (18611-43-3) + trans-1-chloro-3,3,3-trifluoropropene (102687-65-0)

Guidance literature:

With fluorinated activated almina; at 300 ℃; for 0.0166667h;

Reference yield: 31.3%

1,1,3,3-tetrachloro-1-fluoropropane → 1,1,3,3-tetrachloro-1-propene (18611-43-3) + trans-1-chloro-3,3,3-trifluoropropene (102687-65-0)

Guidance literature:

With fluorinated activated almina; at 300 ℃; for 0.0166667h;

Reference yield: 20.5%

1,1,3-trichloro-3,3-difluoropropane (460-63-9) + 1,1,1,3,3-Pentafluoropropane (460-73-1) → 1,3-dichloro-3,3-difluoroprop-1-ene + 1,1,3,3-tetrachloro-1-propene (18611-43-3) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + trans-1-chloro-3,3,3-trifluoropropene (102687-65-0)

Guidance literature:

With fluorinated activated almina; at 200 ℃; for 0.0166667h;

upstream raw materials:

3,3-dichloroacrolein

propene

dichloromethane

Trichloroethylene

Downstream raw materials:

trans-1-chloro-3,3,3-trifluoropropene

1-chloro-3,3,3-trifluoropropene

1-chloro-1,3,3,3-tetrafluoropropane

Refernces

• 1、 -. "Method for eliminating hydrogen chloride by catalytic cracking of chloralkane". Paragraph 0124-0129. . Retrieved 2020/08/06.
• 2、 -. "METHOD FOR PRODUCING 1-CHLORO-3,3,3-TRIFLUOROPROPENE". Paragraph 0050; 0065; 0066. . Retrieved 2020/02/10.