TRI-T-BUTOXYCHLOROSILANE

Base Information

• Chemical Name: TRI-T-BUTOXYCHLOROSILANE
• CAS No.: 18105-64-1
• Molecular Formula: C12H27ClO3Si
• Molecular Weight: 282.883
• Hs Code.: 2931900090
• Mol file: 18105-64-1.mol

Synonyms:Silane,tri-tert-butoxychloro- (6CI,7CI,8CI);Chlorotris(tert-butyloxy)silane;Tri-tert-butoxychlorosilane;Tri-tert-butoxysilyl chloride;Tris(tert-butoxy)(chloro)silane;

Chemical Property of TRI-T-BUTOXYCHLOROSILANE

Chemical Property:

• Vapor Pressure: 0.034mmHg at 25°C
• Refractive Index: 1.434
• Boiling Point: 250.719 °C at 760 mmHg
• Flash Point: 88.626 °C
• PSA: 27.69000
• Density: 0.966 g/cm³
• LogP: 4.10610

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRI-T-BUTOXYCHLOROSILANE

There total 8 articles about TRI-T-BUTOXYCHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

potassium tert-butylate (865-47-4) → tri-tert-butoxy-chloro-silane (18105-64-1)

Guidance literature:

potassium tert-butylate; With tetrachlorosilane; In hexane; at 0 ℃; for 1h; Inert atmosphere; Cooling with ice;

In hexane; at 20 ℃; for 2h; Inert atmosphere;

In hexane; Inert atmosphere; Reflux;

DOI:10.1039/c9dt04230j

Reference yield: 67.0%

di-t-butoxydichlorosilane (18395-80-7) + tert-butyl alcohol (75-65-0) → tri-tert-butoxy-chloro-silane (18105-64-1)

Guidance literature:

With pyridine; In pyridine;

Reference yield: 62.0%

tetrachlorosilane (10026-04-7,53609-55-5) + sodium t-butanolate (865-48-5) → tri-tert-butoxy-chloro-silane (18105-64-1)

Guidance literature:

In petroleum ether;

upstream raw materials:

sodium t-butanolate

di-t-butoxydichlorosilane

tert-butyl alcohol

pyridine

Downstream raw materials:

tetraethylammonium chloride

tri(tert-butoxy)silyl cyanide

tri(tert-butoxy)silyl isocyanide

Refernces

• 1、 Gompa, Thaige P.,Jiang, Ningxin,Bacsa, John,La Pierre, Henry S.. "Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes: Via oxidative transmetallation". . p. 16869 - 16872. Retrieved 2019.