1,2,3,4-Tetrahydroanthracene

Base Information

• Chemical Name: 1,2,3,4-Tetrahydroanthracene
• CAS No.: 2141-42-6
• Molecular Formula: C14H14
• Molecular Weight: 182.265
• Hs Code.: 2902909090
• European Community (EC) Number: 218-392-9
• DSSTox Substance ID: DTXSID00175681
• Nikkaji Number: J149.666B
• Wikidata: Q83046010
• Mol file: 2141-42-6.mol

Synonyms:1,2,3,4-Tetrahydroanthracene;2141-42-6;Anthracene, 1,2,3,4-tetrahydro-;Anthracene, tetrahydro-;EINECS 218-392-9;DTXSID00175681;1,2,3,4-Tetrahydroanthracene #;FT-0778166

Chemical Property of 1,2,3,4-Tetrahydroanthracene

Chemical Property:

• Vapor Pressure: 0.000482mmHg at 25°C
• Melting Point: 103-105 °C
• Refractive Index: 1.4850 (estimate)
• Boiling Point: 323.8°Cat760mmHg
• Flash Point: 156.5°C
• PSA: 0.00000
• Density: 1.069g/cm³
• LogP: 3.71860
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 182.109550447
• Heavy Atom Count: 14
• Complexity: 174

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC2=CC3=CC=CC=C3C=C2C1

Technology Process of 1,2,3,4-Tetrahydroanthracene

There total 136 articles about 1,2,3,4-Tetrahydroanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.2%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0) + 9,10-dihydro-9-methylanthracene (17239-99-5) + 1,2,3,4-tetrahydroanthracene (2141-42-6)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; titanium tetrachloride; In diethylene glycol dimethyl ether; at 200 ℃; for 18h; under 67505.4 Torr;

Reference yield: 68.0%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0) + 1,2,3,4-tetrahydroanthracene (2141-42-6)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; In n-heptane; at 200 ℃; for 16h; under 67505.4 Torr;

Reference yield: 52.3%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0) + 1,2,3,4,5,6,7,8,9,10-hexahydroanthracene (3485-60-7) + 1,2,3,4-tetrahydroanthracene (2141-42-6) + 1,2,3,4,5,6,7,8-octahydroanthracene (1079-71-6)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; titanium tetrachloride; In n-heptane; at 200 ℃; for 3h; under 67505.4 Torr; Further byproducts given;

upstream raw materials:

9,10-dihydroanthracene

tetralin

anthracene

1-hydroxyanthracene

Downstream raw materials:

1,2,3,4,5,6,7,8-octahydroanthracene

1-(5,6,7,8-tetrahydro-[2]anthryl)-butan-1-one

phenanthrene

9,10-dihydrophenanthrene

Refernces

• 1、 Watanabe, Takashi,Geib, Steven J.,Curran, Dennis P.,Taniguchi, Tsuyoshi. "N-Heterocyclic Carbene Boranes are Hydrogen Donors in Masamune-Bergman Reactions of Benzo[3,4]cyclodec-3-ene-1,5-diynes". . p. 13034 - 13042. Retrieved 2017.
• 2、 Schmid,Karrer. "-". . p. 1067,1072. Retrieved 1948.
• 3、 Funk,Young,Williams,Flanagan,Cecil. "Photochemical cycloaromatization reactions of ortho-dialkynylarenes: A new class of DNA photocleaving agents". . p. 3291 - 3292. Retrieved 1996.
• 4、 Bakhvalova, Elena S.,Bykov, Alexey V.,Demidenko, Galina N.,Kiwi-Minsker, Lioubov,Mikheev, Alexey V.,Nikoshvili, Linda Z.,Pinyukova, Arina O.,Sulman, Mikhail G.. "Noble metal nanoparticles stabilized by hyper-cross-linked polystyrene as effective catalysts in hydrogenation of arenes". . . Retrieved 2021/08/13.
• 5、 Han, Bo,Jiao, Hongmei,Ma, Haojie,Wang, Jijiang,Zhang, Miaomiao,Zhang, Yuqi. "Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts". . p. 39934 - 39939. Retrieved 2021/12/31.