Magnesium;dodecane;bromide

Base Information

• Chemical Name: Magnesium;dodecane;bromide
• CAS No.: 15890-72-9
• Molecular Formula: C12H25BrMg
• Molecular Weight: 273.539
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID50394800
• Mol file: 15890-72-9.mol

Synonyms:magnesium;dodecane;bromide;DTXSID50394800

Chemical Property of Magnesium;dodecane;bromide

Chemical Property:

• Flash Point: <−30 °F
• PSA: 0.00000
• Density: 0.843 g/mL at 25 °C
• LogP: 5.72050
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 272.09901
• Heavy Atom Count: 14
• Complexity: 66.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dodecylmagnesium bromide solution 1.0 M in diethyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+,C
• Hazard Codes: F+,C,F
• Statements: 12-14-20/21/22-34-40-67-22-19-17-11
• Safety Statements: 16-26-33-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC[CH2-].[Mg+2].[Br-]
• Uses: Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Technology Process of Magnesium;dodecane;bromide

There total 3 articles about Magnesium;dodecane;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl ether (60-29-7,927820-24-4) + 1-Iodododecane (4292-19-7) → dodecane (112-40-3) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + tetracosane (646-31-1) + laurylmagnesium bromide (15890-72-9)

Guidance literature:

Product distribution;

Reference yield:

1-dodecylbromide (143-15-7) → laurylmagnesium bromide (15890-72-9)

Guidance literature:

With magnesium; In tetrahydrofuran; for 2.5h; Heating;

DOI:10.1002/jhet.5570390519

Reference yield:

1-dodecylbromide (143-15-7) → laurylmagnesium bromide (15890-72-9)

Guidance literature:

With diethyl ether;

upstream raw materials:

diethyl ether

1-Iodododecane

1-dodecylbromide

Downstream raw materials:

2,3-dimethyl-pentadecane

dodecane

1-dodecene

tetracosane

Refernces

• 1、 Zhang, Haiming,Gong, Zhongmiao,Sun, Kewei,Duan, Ruomeng,Ji, Penghui,Li, Ling,Li, Chen,Müllen, Klaus,Chi, Lifeng. "Two-Dimensional Chirality Transfer via On-Surface Reaction". supporting information. p. 11743 - 11748. Retrieved 2016/09/23.