Cerium(III) oxalate

Base Information

• Chemical Name: Cerium(III) oxalate
• CAS No.: 15750-47-7
• Molecular Formula: 3C₂O₄*2Ce*8H₂O
• Molecular Weight: 688.421
• European Community (EC) Number: 629-618-4
• UNII: 0UV74P3R0J
• Wikidata: Q27237275
• Mol file: 15750-47-7.mol

Synonyms:Cerous oxalate nonahydrate;13266-83-6;Cerium(III) oxalate;cerium(3+);oxalate;nonahydrate;UNII-0UV74P3R0J;0UV74P3R0J;Cerium(iii)oxalate nonahydrate;CERIUM(III) OXALATE NONAHYDRATE;Oxalic acid, cerium(3) salt (3:2), nonahydrate;Ethanedioic acid, cerium(3) salt (3:2), nonahydrate;CEROCOL;CERIUM OXALICUM;15750-47-7;Cerium oxalate nonahydrate;CERIUM OXALICUM [HPUS];CERIUM(III)OXALATENONAHYDRATE;CEROUS OXALATE NONAHYDRATE [MI];CEROUS OXALATE (CE2(C2O4)3) NONAHYDRATE;Oxalic acid, cerium(2) salt (3:2), heptacosahydrate;Q27237275;Ethanedioic acid, cerium(3) salt (3:2), heptacoshydrate;OXALIC ACID, CERIUM(3+) SALT (3:2), NONAHYDRATE;ETHANEDIOIC ACID, CERIUM(3+) SALT (3:2), NONAHYDRATE

Chemical Property of Cerium(III) oxalate

Chemical Property:

• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 188.8°C
• PSA: 240.78000
• Density: g/cm³
• LogP: -10.54140
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Insoluble in water. Soluble in hot dilute HCl and H{2}SO{4}
• Hydrogen Bond Donor Count: 9
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 0
• Exact Mass: 705.84495
• Heavy Atom Count: 29
• Complexity: 60.5

Purity/Quality:

99% ^*data from raw suppliers

Cerium(III) oxalate hydrate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 21/22
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].O.O.O.O.O.O.O.O.O.[Ce+3].[Ce+3]
• Uses: Cerium Oxalate, in forms of crystalline aggregates, is the important material for catalyst, glass, phosphors and polishing powders. It is used to decolorize glass by keeping iron in its ferrous state. The ability of Cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass. It is applied to optical components to improve performance.

Technology Process of Cerium(III) oxalate

There total 14 articles about Cerium(III) oxalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water (7732-18-5) + oxalic acid (144-62-7,97993-78-7) + cerous nitrate → cerium oxalate decahydrate (6003-86-7,7100-55-2,10171-47-8,13266-83-6,15053-73-3,15750-47-7,35586-22-2)

Guidance literature:

With cetyltrimethylammonim bromide; In water; glycerol; for 0.0833333h; Time; Sonication;

DOI:10.1002/bkcs.11398

Reference yield:

Dimethyl oxalate (553-90-2) → cerium oxalate decahydrate (6003-86-7,7100-55-2,10171-47-8,13266-83-6,15053-73-3,15750-47-7,35586-22-2)

Guidance literature:

With nitric acid; In water; stirring, heating on water bath for 3 h, standing overnight at room temp.; filtrn., washed with ethanol, ether, dried for 24 h in air at room temp.;

DOI:10.1021/ac60133a015

Reference yield:

cerous nitrate → cerium oxalate decahydrate (6003-86-7,7100-55-2,10171-47-8,13266-83-6,15053-73-3,15750-47-7,35586-22-2)

Guidance literature:

With oxalic acid; In water; excess oxalic acid (pptn.); filtration, washing (H2O), drying in air; elem. anal.;

DOI:10.1016/S0020-1693(00)82125-8

upstream raw materials:

cerium

oxalic acid

cerium chloride

Dimethyl oxalate

Downstream raw materials:

cerium(III) oxalate

Refernces

• 1、 Tyrpekl, Vaclav,Markova, Pavlina,Dopita, Milan,Brázda, Petr,Vacca, Mirko A.. "Cerium Oxalate Morphotypes: Synthesis and Conversion into Nanocrystalline Oxide". . p. 10111 - 10118. Retrieved 2019/08/20.
• 2、 Claparede, Laurent,Clavier, Nicolas,Dacheux, Nicolas,Moisy, Philippe,Podor, Renaud,Ravaux, Johann. "Influence of crystallization state and microstructure on the chemical durability of cerium-neodymium mixed oxides". . p. 9059 - 9072. Retrieved 2011/10/17.