Bromotris(triphenylphosphine)copper(I)

Base Information

• Chemical Name: Bromotris(triphenylphosphine)copper(I)
• CAS No.: 15709-74-7
• Molecular Formula: C54H45BrCuP3
• Molecular Weight: 930.323
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID60460045
• Mol file: 15709-74-7.mol

Synonyms:Bromotris(triphenylphosphine)copper(I);15709-74-7;bromocopper;triphenylphosphane;Copper, bromotris(triphenylphosphine)-, (T-4)-;MFCD04118115;CuBr(PPh3)3;DTXSID60460045;QXLPGKOIQZWUPL-UHFFFAOYSA-M;AKOS027320672;bromotris(triphenylphosphine)copper (1);SY117567;Bromotris(triphenylphosphine)copper(I), 98%;FT-0688272;D77723;A883524;J-009378

Chemical Property of Bromotris(triphenylphosphine)copper(I)

Chemical Property:

• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 168-170 °C(lit.)
• Boiling Point: 360 °C at 760 mmHg
• Flash Point: 181.7 °C
• PSA: 40.77000
• LogP: 11.17750
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 928.12135
• Heavy Atom Count: 59
• Complexity: 204

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bromotris(triphenylphosphine)copper(I) 98% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cu]Br

Technology Process of Bromotris(triphenylphosphine)copper(I)

There total 4 articles about Bromotris(triphenylphosphine)copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

triphenylphosphine (603-35-0) + copper(ll) bromide (7789-45-9) → bromotris(triphenylphosphine)copper(I) (15709-74-7)

Guidance literature:

In methanol; for 0.5h; Heating / reflux;

Reference yield: 90.0%

triphenylphosphine (603-35-0) + copper(I) bromide (7787-70-4) → bromotris(triphenylphosphine)copper(I) (15709-74-7)

Guidance literature:

In methanol; for 4 - 5h;

DOI:10.1134/S1070363218030246

Reference yield:

copper(I) bromide (7787-70-4) → bromotris(triphenylphosphine)copper(I) (15709-74-7)

Guidance literature:

With triphenylphosphine; In dichloromethane; stoich. amts. Ph3P and CuBr mixed in small volume methylene chloride; pentane, hexane or cyclohexane added until ppt. began to form, soln. cooled in ice bath and allowed to stand for a few minutes and filtered;

upstream raw materials:

triphenylphosphine

copper(ll) bromide

copper(I) bromide

Downstream raw materials:

[(P(C₆H₅)3)2Cu(C₃H₄N₂)Br]

copper(I)(1,3-thiazolidine-2-thione)-bis(triphenylphosphine) bromide

(triphenylphosphine)(2,2'-bipyridine)copper(I) bromide

(1,10-phenanthroline)(triphenylphosphine)CuBr

Refernces

• 1、 Babgi, Bandar A.,Bawazeer, Musab,Alzaidi, Najah A.,Arshad, Muhammad N.,Jedidi, Abdesslem,Bataweel, Noor M.,Al-Hejin, Ahmed M.,Hussien, Mostafa A.. "Synthesis, characterization, theoretical, and antimicrobial studies of indenoquinoxalin-based ligands and their reactions with CuBr(PPh3)3". . . Retrieved 2021.
• 2、 Davies, Huw M. L.,Hatridge, Taylor A.,Jones, Christopher W.,Liu, Wenbin,Yoo, Chun-Jae. "Optimized Immobilization Strategy for Dirhodium(II) Carboxylate Catalysts for C?H Functionalization and Their Implementation in a Packed Bed Flow Reactor". . p. 19525 - 19531. Retrieved 2020.
• 3、 Alsaedi, Sammar,Babgi, Bandar A.,Abdellattif, Magda H.,Arshad, Muhammad N.,Emwas, Abdul-Hamid M.,Jaremko, Mariusz,Humphrey, Mark G.,Asiri, Abdullah M.,Hussien, Mostafa A.. "Dna-binding and cytotoxicity of copper(I) complexes containing functionalized dipyridylphenazine ligands". . . Retrieved 2021/06/06.