BROMO(1,10-PHENANTHROLINE)(TRIPHENYLPHOSPHINE)COPPER (I)

Base Information

• Chemical Name: BROMO(1,10-PHENANTHROLINE)(TRIPHENYLPHOSPHINE)COPPER (I)
• CAS No.: 25753-84-8
• Molecular Formula: C30H23 Br Cu N2 P
• Molecular Weight: 585.95
• Mol file: 25753-84-8.mol

Synonyms:Copper,bromo(1,10-phenanthroline)(triphenylphosphine)- (8CI); Copper, bromo(1,10-phenanthroline-N1,N10)(triphenylphosphine)-,(T-4)-; Bromo(1,10-phenanthroline)(triphenylphosphine)copper;Bromo(1,10-phenanthroline-N,N')(triphenylphosphine)copper(I)

Chemical Property of BROMO(1,10-PHENANTHROLINE)(TRIPHENYLPHOSPHINE)COPPER (I)

Chemical Property:

• PSA: 39.37000
• LogP: 7.07090

Purity/Quality:

98%Min ^*data from raw suppliers

Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I), min. 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BROMO(1,10-PHENANTHROLINE)(TRIPHENYLPHOSPHINE)COPPER (I)

There total 14 articles about BROMO(1,10-PHENANTHROLINE)(TRIPHENYLPHOSPHINE)COPPER (I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,10-Phenanthroline (66-71-7) + bromotris(triphenylphosphine)copper(I) (15709-74-7) → (1,10-phenanthroline)(triphenylphosphine)CuBr (25753-84-8)

Guidance literature:

In chloroform;

DOI:10.1002/ejic.201402161

Reference yield:

{(1,10-phenanthroline)2Cu}{(HO)3B(formate)} + benzyl bromide (100-39-0) → (1,10-phenanthroline)(triphenylphosphine)CuBr (25753-84-8) + {(1,10-phenanthroline)2Cu}(formate) (114487-18-2) + benzyl formate (104-57-4)

Guidance literature:

With P(C₆H₅)3; In methanol; under N2, reaction time: 2 h; evapn. to dryness, treated with diethyl ether, insoluble product: Cu-compd., ester was contained in the mother liquor (gas chromy.);

DOI:10.1016/S0020-1693(00)83696-8

Reference yield:

(1,10-phenanthroline)(triphenylphosphine)Cu(formate) (32474-61-6) + benzyl bromide (100-39-0) → (1,10-phenanthroline)(triphenylphosphine)CuBr (25753-84-8) + benzyl formate (104-57-4)

Guidance literature:

In dichloromethane; under N2, reaction time: 2 h; evapn. to dryness, treated with diethyl ether, insoluble product: Cu-compd., ester was contained in the ether phase (gas chromy.);

DOI:10.1016/S0020-1693(00)83696-8

upstream raw materials:

(1,10-phenanthroline)(triphenylphosphine)Cu(formate)

benzyl bromide

1,10-Phenanthroline

bromotris(triphenylphosphine)copper(I)

Downstream raw materials:

{(1,10-phenanthroline)(CyNC)2Cu}{BPh₄}

(1,10-phenanthroline)(triphenylphosphine)Cu(formate)

(1,10-phenanthroline)(triphenylphosphine)Cu(O-methyl-dithiocarbonate)

(1,10-phenanthroline)(triphenylphosphine)Cu(bicarbonate)

Refernces

• 1、 Mashat, Khlood H.,Babgi, Bandar A.,Hussien, Mostafa A.,Nadeem Arshad, Muhammad,Abdellattif, Magda H.. "Synthesis, structures, DNA-binding and anticancer activities of some copper(I)-phosphine complexes". . p. 164 - 172. Retrieved 2018/11/23.
• 2、 -. "Methods and systems for preparing fused heterocyclic compounds using copper(I) catalysts". Page/Page column 15. . Retrieved 2009/01/24.