Nickel(II) formate dihydrate

Base Information

• Chemical Name: Nickel(II) formate dihydrate
• CAS No.: 15694-70-9
• Molecular Formula: 2CHO₂*2H₂O*Ni
• Molecular Weight: 184.756
• DSSTox Substance ID: DTXSID101345082
• Mol file: 15694-70-9.mol

Synonyms:nickel(ii) formate dihydrate;15694-70-9;nickel(2+);diformate;dihydrate;nickel(ii)formatedihydrate;nickelous diformate dihydrate;DTXSID101345082

Chemical Property of Nickel(II) formate dihydrate

Chemical Property:

• Melting Point: 130-140°C -2H₂O
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 52.60000
• Density: g/cm³
• LogP: 0.51920
• Water Solubility.: In the range 180-200° decomposes to Ni, CO, CO{2}, H{2}, H{2}O, CH{4}. Partially soluble in water
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 183.951780
• Heavy Atom Count: 9
• Complexity: 7.5

Purity/Quality:

98%Min ^*data from raw suppliers

Nickel(II)Formate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-].C(=O)[O-].O.O.[Ni+2]
• Uses: Nickel(II) formate dihydrate is used in nickel catalyst preparations. It is also used as a biochemical for proteomics research.

Technology Process of Nickel(II) formate dihydrate

There total 16 articles about Nickel(II) formate dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

nickel(II) sulphate → nickel formate dihydrate (14975-42-9,15694-70-9,22829-48-7,64714-22-3)

Guidance literature:

In water; with intermediate formation of bas. Ni carbonate;;

Reference yield: 95.0%

nickel(II) carbonate (719261-06-0) + formic acid (64-18-6) + water (7732-18-5) → nickel formate dihydrate (14975-42-9,15694-70-9,22829-48-7,64714-22-3)

Guidance literature:

for 1h;

DOI:10.1021/jacs.7b01625

Reference yield: 84.0%

nickel(II) carbonate (719261-06-0) + formic acid (64-18-6) → nickel formate dihydrate (14975-42-9,15694-70-9,22829-48-7,64714-22-3)

Guidance literature:

In water; for 4h; Reflux;

DOI:10.1002/hlca.201800227

upstream raw materials:

formic acid

formate

nickel

nickel dibromide

Downstream raw materials:

nickel(II) oxide

nickel

carbon dioxide

carbon monoxide

Refernces

• 1、 Margossian, Tigran,Larmier, Kim,Allouche, Florian,Chan, Ka Wing,Copéret, Christophe. "Metal(II) Formates (M = Fe, Co, Ni, and Cu) Stabilized by Tetramethylethylenediamine (tmeda): Convenient Molecular Precursors for the Synthesis of Supported Nanoparticles". . . Retrieved 2019/03/13.
• 2、 Matelková, Kristína,Bo?a, Roman,Dlháň, ?ubor,Herchel, Radovan,Moncol, Ján,Svoboda, Ingrid,Ma?lejová, Anna. "Dinuclear and polymeric (μ-formato)nickel(II) complexes: Synthesis, structure, spectral and magnetic properties". . p. 45 - 53. Retrieved 2015/05/05.