ACRYLOXYTRIMETHYLSILANE

Base Information

• Chemical Name: ACRYLOXYTRIMETHYLSILANE
• CAS No.: 13688-55-6
• Molecular Formula: C6H12O2Si
• Molecular Weight: 144.246
• Hs Code.: 29319090
• Mol file: 13688-55-6.mol

Synonyms:Acrylicacid, trimethylsilyl ester (7CI,8CI);Silanol, trimethyl-, acrylate (6CI);SIA0320;SIA 0320.0;Trimethylsilyl 2-propenoate;Trimethylsilyl acrylate;

Chemical Property of ACRYLOXYTRIMETHYLSILANE

Chemical Property:

• Vapor Pressure: 23.1mmHg at 25°C
• Refractive Index: n20/D 1.4090(lit.)
• Boiling Point: 111.1 °C at 760 mmHg
• Flash Point: 17.6 °C
• PSA: 26.30000
• Density: 0.89 g/cm³
• LogP: 1.55050
• Storage Temp.: below 5° C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethylsilyl acrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,N
• Hazard Codes: Xi,N,F
• Statements: 36/37/38-51/53-11
• Safety Statements: 26-28-61

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ACRYLOXYTRIMETHYLSILANE

There total 8 articles about ACRYLOXYTRIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

chloro-trimethyl-silane (75-77-4) + acrylic acid (79-10-7) → trimethylsilyl acrylate (13688-55-6)

Guidance literature:

With 1-methyl-1H-imidazole; at 50 - 85 ℃;

Reference yield: 87.9%

chloro-trimethyl-silane (75-77-4) + sodium 2-propenoate (7446-81-3) + acrylic acid (79-10-7) → trimethylsilyl acrylate (13688-55-6)

Guidance literature:

chloro-trimethyl-silane; acrylic acid; With 4-methoxy-phenol; at 70 ℃; for 4h; Inert atmosphere;

sodium 2-propenoate; at 20 ℃; for 0.5h; Inert atmosphere;

Reference yield: 85.0%

2-methyl-5-<1-(trimethylsiloxy)vinyl>furan (83796-14-9) + acrylic acid (79-10-7) → 2-acetyl-5-methylfuran (1193-79-9) + trimethylsilyl acrylate (13688-55-6)

Guidance literature:

at 35 ℃; for 24h;

upstream raw materials:

chloro-trimethyl-silane

sodium 2-propenoate

acrylic acid

2-methyl-5-<1-(trimethylsiloxy)vinyl>furan

Downstream raw materials:

allyl acrylate

1,1,1,5,5,5-hexamethyl-3,3-diphenyltrisiloxane

3-phenyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

1,1,5,5,5-hexamethyl-3-phenyl-3-[(trimethylsilyl)oxy]trisiloxane

Refernces

• 1、 Rakhlin,Gostevskii,Fomina,Mirskov,Makarova,Lopyrev,Voronkov. "Synthesis of trimethylsilyl β-(2,2-dimethylhydrazino)propionate". . p. 127 - 128. Retrieved 2004.
• 2、 -. "Synthetic method of allyl acrylate". Paragraph 0018; 0019. . Retrieved 2017/04/28.