Copper 8-quinolinolate

Base Information

• Chemical Name: Copper 8-quinolinolate
• CAS No.: 13014-03-4
• Molecular Formula: C9H7 N O . x Cu
• Molecular Weight: 351.851
• Hs Code.: 2933499090
• European Community (EC) Number: 233-841-9,625-178-2
• ICSC Number: 0756
• UN Number: 3077
• Mol file: 13014-03-4.mol

Synonyms:bis(8-quinolinolato)copper(II);copper oxinate;copper(II) oxinate;Cu 8Q;cupric 8-quinolinoxide

Chemical Property of Copper 8-quinolinolate

Chemical Property:

• Melting Point: 240 °C (dec.)(lit.)
• PSA: 71.90000
• LogP: 4.75470
• Storage Temp.: 0-6°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 207.982361
• Heavy Atom Count: 12
• Complexity: 138

Purity/Quality:

99% ^*data from raw suppliers

8-HydroxyquinolineCopperSalt ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,T+
• Statements: 36/37/38-26
• Safety Statements: 26-36-45-36/37-28

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Pesticides -> Fungicides
• Canonical SMILES: C1=CC2=C(C(=C1)O)N=CC=C2.[Cu]
• Inhalation Risk: A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
• Effects of Short Term Exposure: The substance is irritating to the eyes and possibly the respiratory tract.
• Uses: 8-Hydroxyquinoline Copper Salt is used in the formulation of biocide microcapsules towards stabilized iodine-?containing compounds for protection of technical materials from degradation by microorganisms.

Technology Process of Copper 8-quinolinolate

There total 6 articles about Copper 8-quinolinolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

8-quinolinol (148-24-3,24804-14-6) + copper(II) formate tetrahydrate (5893-61-8,14690-98-3,15305-21-2,16842-73-2,22992-79-6,34729-06-1,133386-02-4,133386-04-6) → copper 8-hydroxyquinolinate (13014-03-4)

Guidance literature:

at 80 - 100 ℃; for 1h; under 0.000750075 Torr; Time; Large scale;

Reference yield: 99.3%

8-quinolinol (148-24-3,24804-14-6) + copper(ll) sulfate pentahydrate → copper 8-hydroxyquinolinate (13014-03-4)

Guidance literature:

With sodium hydroxide; In water; at 40 - 90 ℃; for 1h;

Reference yield:

quinoline (91-22-5) → copper 8-hydroxyquinolinate (13014-03-4)

Guidance literature:

Multi-step reaction with 3 steps

1: sulfuric acid / 2 h / 100 - 140 °C

2: sodium hydroxide; water / 10 - 345 °C

3: sodium hydroxide / water / 1 h / 40 - 90 °C

With sulfuric acid; water; sodium hydroxide; In water;

upstream raw materials:

8-quinolinol

copper

copper(II) acetate monohydrate

quinoline

Downstream raw materials:

(tetraphenylporphyrin)copper(II)

Refernces

• 1、 -. "Method for directly preparing light-emitting material, namely 8- hydroxyquinoline copper, of light-emitting material". Paragraph 0029-0034. . Retrieved 2020/02/08.
• 2、 -. "Termite-controlling agent composition". . . Retrieved 2008/06/13.