Copper tetraphenylporphyrin

Base Information

• Chemical Name: Copper tetraphenylporphyrin
• CAS No.: 14172-91-9
• Molecular Formula: C44H28CuN4
• Molecular Weight: 676.279
• Hs Code.: 29339900
• European Community (EC) Number: 238-019-3
• Mol file: 14172-91-9.mol

Synonyms:copper tetraphenylporphyrin

Chemical Property of Copper tetraphenylporphyrin

Chemical Property:

• PSA: 34.58000
• LogP: 6.43530
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 675.160994
• Heavy Atom Count: 49
• Complexity: 1250

Purity/Quality:

98%,99%, ^*data from raw suppliers

Copper(II) Tetraphenylporphyrin ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)[N-]3.[Cu+2]

Technology Process of Copper tetraphenylporphyrin

There total 82 articles about Copper tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + copper diacetate (142-71-2) → (tetraphenylporphyrin)copper(II) (14172-91-9)

Guidance literature:

In solid; High Pressure; 2000 MPa at room temp.; extrd. (chloroform), chromy.(alumina); UV;

Reference yield: 99.0%

copper(II) acetate dihydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → (tetraphenylporphyrin)copper(II) (14172-91-9)

Guidance literature:

In methanol; chloroform; at 20 ℃;

DOI:10.1016/j.molstruc.2019.04.013

Reference yield: 93.5%

copper diacetate (142-71-2) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → (tetraphenylporphyrin)copper(II) (14172-91-9)

Guidance literature:

In N,N-dimethyl-formamide; at 150 ℃; for 0.5h;

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

(N-ethyl-5,10,15,20-tetraphenylporphinato)copper(II) trifluoromethanesulfonate

dibutylamine

5,15,10,20-tetraphenylporphyrin

Downstream raw materials:

(2-nitro-5,10,15,20-tetraphenylporphyrinato)copper(II)

copper tetraphenylporphyrin benzene solvate

copper(II) 2-formyl-5,10,15,20-tetraphenylporphyrin

2-Formyl-21,23-dihydro-5,10,15,20-tetraphenylporphyrin

Refernces

• 1、 Liao, Ping-Yong,Wang, Xin-Rong,Gao, Ying-Hua,Zhang, Xiang-Hua,Zhang, Li-Jun,Song, Chun-Hong,Zhang, Dan-Ping,Yan, Yi-Jia,Chen, Zhi-Long. "Synthesis, photophysical properties and biological evaluation of β-alkylaminoporphyrin for photodynamic therapy". . p. 6040 - 6047. Retrieved 2016.
• 2、 Aparici Plaza, Luis,Chojnacki, Jaroslaw. "Influence of chloro-form on crystalline products yielded in reactions of 5,10,15,20-tetra-phenyl-porphyrin with HCl and copper(II) salts". . p. m24-m28. Retrieved 2012.
• 3、 Pukhovskaya,Nam, Dao Tkhe,Fien, Chan Ding,Domanina,Ivanova, Yu. B.,Semeikin. "Acid–base and coordination properties of Meso-substituted porphyrins in nonaqueous solutions". . p. 1692 - 1702. Retrieved 2017.
• 4、 Rahimi, Rahmatolah,Gholamrezapor, Ensieh,Naimi-Jamal, Mohammad Reza. "Oxidation of benzyl alcohols to the corresponding carbonyl compounds catalyzed by copper (II) meso-tetra phenyl porphyrin as cytochrome P-450 model reaction". . p. 1561 - 1568. Retrieved 2011.
• 5、 Ageeva,Utzig,Golubchikov,Zielenkiewicz. "Thermokinetic studies of porphyrin complexation in non-aqueous solutions by heat conduction microcalorimetry". . p. 243 - 248. Retrieved 1998.
• 6、 Tsai, Cheng-Hsi,Tung, Jo-Yu,Chen, Jyh-Horung,Liao, Feng-Ling,Wang, Sue-Lein,Wang, Shin-Shin,Hwang, Lian-Pin,Chen, Chie-Bein. "Crystal of meso-p-tolyl-porphyrinato copper(II) Cu(tptp) and di-cation ion-pair complex [H4tptp]2+ [CF3SO3]2- formation during the reaction of Cu(CF3SO3)2 with meso-p-tolyl-porphyrin in CDCl3". . p. 633 - 639. Retrieved 2000.
• 7、 Zvezdina,Mal'Tseva,Chizhova,Scheblykin,Mamardashvili. "Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide". . p. 486 - 490. Retrieved 2013.
• 8、 Inamo,Kamiya,Inada,Nomura,Funahashi. "Structural characterization and formation kinetics of sitting-atop (SAT) complexes of some porphyrins with copper(II) ion in aqueous acetonitrile relevant to porphyrin metalation mechanism. Structures of aquacopper(II) and Cu(II)-SAT complexes as determined by XAFS spectroscopy". . p. 5636 - 5644. Retrieved 2001.
• 9、 Al-Shewiki, Rasha K.,Korb, Marcus,Hildebrandt, Alexander,Zahn, Stefan,Naumov, Sergej,Buschbeck, Roy,Rüffer, Tobias,Lang, Heinrich. "Diaqua-β-octaferrocenyltetraphenylporphyrin: A multiredox-active and air-stable 16π non-aromatic species". . p. 1578 - 1585. Retrieved 2019.
• 10、 Sun, Sai,Yang, Xiaoxuan,Li, Siqi,Chen, Xinyu,Li, Ke,Lv, Jiaqi,Wang, Wenwen,Cheng, Dongming,Wang, Yong-Hui,Zang, Hong-Ying. "Single-atom metal-N4site molecular electrocatalysts for ambient nitrogen reduction". . p. 2589 - 2596. Retrieved 2021/04/22.