2-NITRO-5 10 15 20-TETRAPHENYL-21H 23H-&

Base Information

• Chemical Name: 2-NITRO-5 10 15 20-TETRAPHENYL-21H 23H-&
• CAS No.: 71147-55-2
• Molecular Formula: C44H27 Cu N5 O2
• Molecular Weight: 721.277
• Mol file: 71147-55-2.mol

Synonyms:Copper,[2-nitro-5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-2)-; 21H,23H-Porphine, 2-nitro-5,10,15,20-tetraphenyl-, copper complex;(2-Nitro-5,10,15,20-tetraphenylporphinato)copper;(2-Nitro-5,10,15,20-tetraphenylporphyrinato)copper;(2-Nitro-5,10,15,20-tetraphenylporphyrinato)copper(II); Copper2-Nitro-5,10,15,20-tetraphenylporphyrin

Chemical Property of 2-NITRO-5 10 15 20-TETRAPHENYL-21H 23H-&

Chemical Property:

• Melting Point: >300 °C(lit.)
• PSA: 86.31000
• LogP: 7.18120

Purity/Quality:

97% ^*data from raw suppliers

2-NITRO-5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE COPPER(II) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-NITRO-5 10 15 20-TETRAPHENYL-21H 23H-&

There total 8 articles about 2-NITRO-5 10 15 20-TETRAPHENYL-21H 23H-& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetraphenylporphyrin Cu(II) complex (14172-91-9) → (2-nitro-5,10,15,20-tetraphenylporphyrinato)copper(II) (71147-55-2)

Guidance literature:

With Nitrogen dioxide; In not given; in trichloroethylene, CH2Cl2, benzene, benzene/hexane, or CH2Cl2/MeCN at room temp.;

DOI:10.1039/c39840001535

Reference yield: 98.0%

copper(II) nitrate trihydrate + (tetraphenylporphyrin)copper(II) (14172-91-9) → Cu(2+)-nitro-α,β,γ,δ-tetraphenylporphine (71147-55-2)

Guidance literature:

With acetic anhydride; acetic acid; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.dyepig.2019.107760

Reference yield: 96.0%

(tetraphenylporphyrin)copper(II) (14172-91-9) → Cu(2+)-nitro-α,β,γ,δ-tetraphenylporphine (71147-55-2)

Guidance literature:

With copper(II) nitrate trihydrate; acetic anhydride; acetic acid; In dichloromethane; for 4h; Reflux;

DOI:10.1016/j.bmc.2016.09.060

upstream raw materials:

5,10,15,20-tetraphenylporphyrin Cu(II) complex

(tetraphenylporphyrin)copper(II)

5,15,10,20-tetraphenylporphyrin

nitric acid

Downstream raw materials:

[Co(NC₄H₂)3(C(C₆H₅))4NC₄N₂C₁₂H₆N₂]

[Ni(NC₄H₂)3(C(C₆H₅))4NC₄N₂C₁₂H₆N₂]

[Zn(NC₄H₂)3(C(C₆H₅))4NC₄N₂C₁₂H₆N₂]

[Cu(NC₄H₂)3(C(C₆H₅))4NC₄N₂C₁₂H₆N₂]

Refernces

• 1、 Ol'shevskaya, Valentina A.,Alpatova, Viktoriya M.,Radchenko, Alexandra S.,Ramonova, Alla A.,Petrova, Albina S.,Tatarskiy, Victor V.,Zaitsev, Andrei V.,Kononova, Elena G.,Ikonnikov, Nikolay S.,Kostyukov, Alexey A.,Egorov, Anton E.,Moisenovich, Mikhail M.,Kuzmin, Vladimir A.,Bragina, Natalya A.,Shtil, Alexander A.. "β-Maleimide substituted meso-arylporphyrins: Synthesis, transformations, physico-chemical and antitumor properties". . . Retrieved 2019/08/12.
• 2、 Olsson, Sandra,Sch?fer, Clara,Blom, Magnus,Gogoll, Adolf. "Exciton-Coupled Circular Dichroism Characterization of Monotopically Binding Guests in Host?Guest Complexes with a Bis(zinc porphyrin) Tweezer". . p. 1169 - 1178. Retrieved 2019/01/04.