Technology Process of (N-ethyl-5,10,15,20-tetraphenylporphinato)copper(II) trifluoromethanesulfonate
There total 1 articles about (N-ethyl-5,10,15,20-tetraphenylporphinato)copper(II) trifluoromethanesulfonate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2,2,6,6-tetramethyl-piperidine;
In
acetonitrile;
ligand was dissolved in dry CH3CN containing 3-fold excess of Cu salt, 2,2,6,6-tetramethylpiperidine was added, stirred for 1 h; filtered, evapd. by rotary evapn., washed with water, extd. into CH2Cl2, dried over Na2SO4, purified by flash chromy. with 2-3% MeOH in CH2Cl2 as eluent, recovered by flash rotary evaporator , stored in freezer; elem. anal.;
- Guidance literature:
-
In
acetonitrile;
byproducts: di-n-butylethylamine; 2-fold excess of (n-Bu)2NH, 2.5 d at 30-45°C, soln. was made alkaline with solid NaOH; monitored spectrophotometrically;
Kinetics;