Technology Process of C12H10O5
There total 1 articles about C12H10O5 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
N-ethyl-N,N-diisopropylamine;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 6h;
DOI:10.1021/ol991067y
- Guidance literature:
-
Multi-step reaction with 6 steps
1: NEt3 / tetrahydrofuran
2: diethyl ether / 24 h / -15 - -5 °C
3: 74 percent / Rh2(OAc)4 / CH2Cl2 / 5 h / 20 °C
4: 93 percent / aq. HCl / dioxane / 3 h / 20 °C
5: 68 percent / NaH / dimethylformamide / 50 °C
6: 150 °C
With
sodium hydride; triethylamine;
hydrogenchloride; dirhodium tetraacetate;
In
tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
6: retro-hetero Diels-Alder reaction;
DOI:10.1021/ol991067y
- Guidance literature:
-
Multi-step reaction with 7 steps
1: NEt3 / tetrahydrofuran
2: diethyl ether / 24 h / -15 - -5 °C
3: 74 percent / Rh2(OAc)4 / CH2Cl2 / 5 h / 20 °C
4: 93 percent / aq. HCl / dioxane / 3 h / 20 °C
5: 68 percent / NaH / dimethylformamide / 50 °C
6: 150 °C
7: 24 h / 150 °C
With
sodium hydride; triethylamine;
hydrogenchloride; dirhodium tetraacetate;
In
tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
6: retro-hetero Diels-Alder reaction / 7: hetero Diels-Alder reaction;
DOI:10.1021/ol991067y
