9-BUTYLPHENANTHRENE

Base Information

• Chemical Name: 9-BUTYLPHENANTHRENE
• CAS No.: 10394-57-7
• Molecular Formula: C18H18
• Molecular Weight: 234.341
• Hs Code.: 2902909090
• Mol file: 10394-57-7.mol

Synonyms:9-Butylphenanthrene

Chemical Property of 9-BUTYLPHENANTHRENE

Chemical Property:

• PSA: 0.00000
• LogP: 5.33560

Purity/Quality:

98%,99%, ^*data from raw suppliers

9-BUTYLPHENANTHRENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-BUTYLPHENANTHRENE

There total 26 articles about 9-BUTYLPHENANTHRENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phenanthren-9-yl 4-methylbenzenesulfonate + butyl magnesium bromide (693-04-9) → 9-(4-butylphenyl)phenanthrene (10394-57-7)

Guidance literature:

With iron(III)-acetylacetonate; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at 23 ℃; for 1h;

DOI:10.1002/ejoc.201701654

Reference yield: 75.0%

2-(hex-1-yn-1-yl)-1,1′-biphenyl (851901-90-1) → 9-(4-butylphenyl)phenanthrene (10394-57-7)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In 1-methyl-pyrrolidin-2-one; Heating;

DOI:10.1021/ol0620850

Reference yield: 75.0%

2-(2-bromophenyl)-2-oxoacetic acid (26767-16-8) + C12H15I → 9-(4-butylphenyl)phenanthrene (10394-57-7)

Guidance literature:

With trifuran-2-yl-phosphane; palladium diacetate; lithium tert-butoxide; Trimethylacetic acid; In N,N-dimethyl acetamide; at 20 - 120 ℃; for 12.25h; regioselective reaction; Sealed tube;

DOI:10.1021/acs.orglett.1c03517

upstream raw materials:

1-bromo-butane

9-phenanthrylmagnesium bromide

n-butyllithium

diethyl ether

Refernces

• 1、 Piontek, Aleksandra,Och?dzan-Siod?ak, Wioletta,Bisz, Elwira,Szostak, Michal. "Nickel-Catalyzed C(sp2)?C(sp3) Kumada Cross-Coupling of Aryl Tosylates with Alkyl Grignard Reagents". . p. 2329 - 2336. Retrieved 2019.
• 2、 Piontek, Aleksandra,Och?dzan-Siod?ak, Wioletta,Bisz, Elwira,Szostak, Michal. "Cobalt?NHC Catalyzed C(sp2)?C(sp3) and C(sp2)?C(sp2) Kumada Cross-Coupling of Aryl Tosylates with Alkyl and Aryl Grignard Reagents". . p. 202 - 206. Retrieved 2021.
• 3、 Anet,F.A.L.,Bavin,P.M.G.. "-". . p. 2160 - 2164. Retrieved 1963.
• 4、 Sinha, Narayan,Heijnen, Dorus,Feringa, Ben L.,Organ, Michael G.. "Murahashi Cross-Coupling at ?78 °C: A One-Pot Procedure for Sequential C?C/C?C, C?C/C?N, and C?C/C?S Cross-Coupling of Bromo-Chloro-Arenes". supporting information. p. 9180 - 9184. Retrieved 2019/07/04.