9-PHENANTHRYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: 9-PHENANTHRYLMAGNESIUM BROMIDE
• CAS No.: 71112-64-6
• Molecular Formula: C14H9BrMg
• Molecular Weight: 281.434
• Hs Code.: 29310099
• DSSTox Substance ID: DTXSID80496265
• Mol file: 71112-64-6.mol

Synonyms:9-Phenanthrylmagnesium bromide;

Chemical Property of 9-PHENANTHRYLMAGNESIUM BROMIDE

Chemical Property:

• Boiling Point: 65 °C(lit.)
• Flash Point: 1 °F
• PSA: 0.00000
• Density: 0.970 g/mL at 25 °C(lit.)
• LogP: 4.63880
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: It reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 279.97380
• Heavy Atom Count: 16
• Complexity: 228

Purity/Quality:

99% ^*data from raw suppliers

9-Phenanthrylmagnesium bromide 0.5M in THF ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F;C;F+
• Hazard Codes: F,C,F+,Xn
• Statements: 11-14-19-22-34-40-12-36/37
• Safety Statements: 16-23-26-36/37/39-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=[C-]C3=CC=CC=C32.[Mg+2].[Br-]
• Uses: 9-Phenanthrylmagnesium bromide is used as an organic chemical synthesis intermediate.

Technology Process of 9-PHENANTHRYLMAGNESIUM BROMIDE

There total 1 articles about 9-PHENANTHRYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-bromophenanthrene (573-17-1) → 9-phenanthrylmagnesium bromide (71112-64-6)

Guidance literature:

With magnesium;

Reference yield: 99.0%

2-((4-methoxyphenyl)(p-tosyl)methyl)phenol (1422447-30-0) + 9-phenanthrylmagnesium bromide (71112-64-6) → 2-((4-methoxyphenyl)(phenanthren-9-yl)methyl)phenol (796874-07-2)

Guidance literature:

9-phenanthrylmagnesium bromide; With zinc dibromide; In tetrahydrofuran; at 0 ℃; for 0.25h; Schlenk technique; Inert atmosphere;

2-((4-methoxyphenyl)(p-tosyl)methyl)phenol; In tetrahydrofuran; at 60 ℃; for 12h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.8b01428

Reference yield: 97.0%

N-Formylpiperidine (2591-86-8) + 9-phenanthrylmagnesium bromide (71112-64-6) → Phenanthrene-9-carboxaldehyde (4707-71-5)

Guidance literature:

In diethyl ether; for 0.25h; Ambient temperature;

upstream raw materials:

9-bromophenanthrene

Downstream raw materials:

1-[9]phenanthryl-1,2-diphenyl-ethanol

4-oxo-4-[9]phenanthryl-butyric acid

9-(4-butylphenyl)phenanthrene

2-(phenanthrene-9-carbonyl)-benzoic acid

Refernces

• 1、 Mueller, Paul,Pautex, Nicole. "From Dichlorocyclopropanes to Furans and Cyclopentadienes via Vinylcarbenes". . p. 1630 - 1637. Retrieved 2007/10/02.