Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester

Base Information

• Chemical Name: Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester
• CAS No.: 77455-53-9
• Molecular Formula: C₁₁H₁₀ClNO₆
• Molecular Weight: 287.656
• Mol file: 77455-53-9.mol

Synonyms:Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester

Chemical Property of Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester

There total 1 articles about Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

acetic anhydride (108-24-7) + 2-chloro-4-methyl-1-nitrobenzene (38939-88-7) → Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester (77455-53-9)

Guidance literature:

With chromium(VI) oxide; sulfuric acid; In acetic acid; at 5 - 8 ℃;

DOI:10.1039/P19810000423

Reference yield: 78.0%

Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester (77455-53-9) → 3-chloro-4-nitrobenzaldehyde (57507-34-3)

Guidance literature:

With sulfuric acid; In ethanol; water;

DOI:10.1039/P19810000423

Reference yield:

Acetic acid acetoxy-(3-chloro-4-nitro-phenyl)-methyl ester (77455-53-9) → (E)-α,α',3,3'-tetrachloro-4,4'-dinitrostilbene (77455-61-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 78 percent / sulphuric acid / H₂O; ethanol

2: 66 percent / phosphorus pentachloride / 6 h / 90 - 100 °C

3: potassium hydroxide / aq. ethanol / 0.4 h / 28 °C

4: in solution

With potassium hydroxide; phosphorus pentachloride; sulfuric acid; In ethanol; water;

DOI:10.1039/P19810000423

upstream raw materials:

acetic anhydride

2-chloro-4-methyl-1-nitrobenzene

Downstream raw materials:

3-chloro-4-nitrobenzaldehyde

3-chloro-4-nitrobenzylidene dichloride

3-chloro-4-nitrobenzyl chloride

3,3'-dichloro-4,4'-dinitrodiphenylacetylene

Refernces

• 1、 Goh, Swee Hock,Kam, Toh Seok. "Comparative Reactivity of Substituted 4-Nitrobenzylidene Dichlorides with Alkali". . p. 423 - 426. Retrieved 2007/10/02.