4,5-Octanediol

Base Information

• Chemical Name: 4,5-Octanediol
• CAS No.: 22607-10-9
• Molecular Formula: C8H18 O2
• Molecular Weight: 146.23
• Hs Code.: 2905399090
• Mol file: 22607-10-9.mol

Synonyms:4,5-Octanediol

Chemical Property of 4,5-Octanediol

Chemical Property:

• PSA: 40.46000
• LogP: 1.30840

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,5-Octanediol

There total 13 articles about 4,5-Octanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

trans-4-Octene (14850-23-8) → 4,5-epoxyoctane (1439-06-1) + butyroin (496-77-5) + octane-4,5-diol (22607-10-9)

Guidance literature:

With peroxytungstophosphate; sulfuric acid; dihydrogen peroxide; In chloroform; for 24h; Heating;

DOI:10.1246/cl.1992.671

Reference yield:

octane-4,5-dione (5455-24-3) → butyroin (496-77-5) + meso-4,5-octanediol (22520-41-8) + syn-4,5-octanediol (22520-40-7,22520-41-8,22607-10-9,59173-74-9,139165-51-8)

Guidance literature:

With sodium tetrahydroborate; In ethanol; Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1016/S0040-4020(97)10024-2

Reference yield:

ethanol (64-17-5) + butan-1-ol (71-36-3) → octane-4,5-diol (22607-10-9) + trans-2,3-hexanediol (82360-67-6) + (RS,RS)-2,3-hexane diol (82360-68-7) + 2.3-butanediol (513-85-9)

Guidance literature:

at 60 - 70 ℃; for 18h; Yield given. Further byproducts given. Yields of byproduct given; Irradiation; Hg high pressure lamp;

DOI:10.1016/0040-4020(82)80003-3

upstream raw materials:

butan-1-ol

octane-4,5-dione

trans-4-Octene

(Z)-oct-4-ene

Downstream raw materials:

octan-4-one

butyraldehyde

octane-4,5-dione

4-octene

Refernces

• 1、 Barreto, Gaston P.,Alvarez, Elida E.,Eyler, Gladys N.,Canizo, Adriana I.,Allegretti, Patricia E.. "Thermal decomposition of diethylketone cyclic triperoxide in polar solvents". . p. 881 - 886. Retrieved 2014/07/07.
• 2、 Klopstra, Marten,Roelfes, Gerard,Hage, Ronald,Kellogg, Richard M.,Feringa, Ben L.. "Non-heme iron complexes for stereoselective oxidation: Tuning of the selectivity in dihydroxylation using different solvents". . p. 846 - 856. Retrieved 2007/10/03.