N-amino mesitylenesulfonate salt of quinoline

Base Information

• Chemical Name: N-amino mesitylenesulfonate salt of quinoline
• CAS No.: 39996-55-9
• Molecular Formula: C₉H₉N₂*C₉H₁₁O₃S
• Molecular Weight: 344.434
• Mol file: 39996-55-9.mol

Synonyms:N-amino mesitylenesulfonate salt of quinoline

Chemical Property of N-amino mesitylenesulfonate salt of quinoline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-amino mesitylenesulfonate salt of quinoline

There total 1 articles about N-amino mesitylenesulfonate salt of quinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

quinoline (91-22-5) + mesitylenesulfonylhydroxylamine (36016-40-7) → N-amino mesitylenesulfonate salt of quinoline (39996-55-9)

Guidance literature:

In diethyl ether; at 0 ℃; for 3h;

DOI:10.1248/cpb.c21-00673

Reference yield: 96.0%

3-Methoxy-1-(4-bromophenyl)-2-propen-1-one (128352-93-2) + N-amino mesitylenesulfonate salt of quinoline (39996-55-9) → 3-(4-Bromobenzoyl)pyrazolo<1,5-a>quinoline (128353-05-9)

Guidance literature:

With triethylamine; In ethanol; Heating;

Reference yield: 80.0%

N-amino mesitylenesulfonate salt of quinoline (39996-55-9) + p-toluenesulfonyl chloride (98-59-9) → N-p-Toluenesulfonyliminoquinolinium Ylide (30416-54-7)

Guidance literature:

With potassium carbonate; In dichloromethane; for 12h;

upstream raw materials:

quinoline

mesitylenesulfonylhydroxylamine

Downstream raw materials:

3-Benzoylpyrazolo<1,5-a>quinoline

3-(4-Bromobenzoyl)pyrazolo<1,5-a>quinoline

N-p-Toluenesulfonyliminoquinolinium Ylide

Refernces

• 1、 Fujita, Hikaru,Arai, Takanari,Kunishima, Munetaka. "Synthesis of N-Aminated Salts of Aliphatic tert-Amines, (Trialkyl)amidines, and (Pentaalkyl)guanidines by Electrophilic Amination in an Ethereal Solvent". . p. 85 - 88. Retrieved 2022/01/31.