Tribromochlorogermane

Base Information

• Chemical Name: Tribromochlorogermane
• CAS No.: 13536-71-5
• Molecular Formula: Br3ClGe
• Molecular Weight: 347.755
• DSSTox Substance ID: DTXSID80159323
• Wikidata: Q83027627
• Mol file: 13536-71-5.mol

Synonyms:Tribromochlorogermane;13536-71-5;DTXSID80159323

Chemical Property of Tribromochlorogermane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 347.64299
• Heavy Atom Count: 5
• Complexity: 28.4

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Cl[Ge](Br)(Br)Br

Technology Process of Tribromochlorogermane

There total 3 articles about Tribromochlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.8%

germanium (7440-56-4) + Bromotrichloromethane (75-62-7) → germanium tetrabromide (13450-92-5) + trichlorobromogermane (13536-49-7) + chlorotribromogermane (13536-71-5) + germaniumtetrachloride (10038-98-9)

Guidance literature:

In gas; vaporization of Ge (alumina-coated tungsten crucible, 1200-1300°C, 5E-3 Torr), introduction into flask (cooled with liq. N2 during Ge vaporization) together with vapor of org. halide, warming to room temp., standing for 1.5 h; further products; GC-MS, GLC;

DOI:10.1246/bcsj.61.1247

Reference yield: 5.8%

germanium (7440-56-4) + Bromotrichloromethane (75-62-7) → germanium tetrabromide (13450-92-5) + trichlorobromogermane (13536-49-7) + chlorotribromogermane (13536-71-5) + CCl3GeBrCl2 (113365-42-7) + germaniumtetrachloride (10038-98-9)

Guidance literature:

reaction of germanium atoms with organic halide by co-condensation under vac. at 77 K; further products; GC-MASS;

DOI:10.1246/cl.1987.1105

Reference yield:

germanium tetrabromide (13450-92-5) + germaniumtetrachloride (10038-98-9) → trichlorobromogermane (13536-49-7) + chlorotribromogermane (13536-71-5) + dichlorodibromogermane (13550-33-9)

Guidance literature:

In neat (no solvent); investigation of liq. GeBr4-GeCl4 mixt. by raman spectroscopy;;

upstream raw materials:

germanium

Bromotrichloromethane

germanium tetrabromide

germaniumtetrachloride

Refernces

• 1、 Mochida, Kunio,Tashiro, Kumiko. "The Reaction of Germanium Atoms with Organic Halides". . p. 1105 - 1108. Retrieved 2007/10/02.