S,S,S-trimethylsulfonium methanesulfonate

Base Information

• Chemical Name: S,S,S-trimethylsulfonium methanesulfonate
• CAS No.: 15057-22-4
• Molecular Formula: CH₃O₃S*C₃H₉S
• Molecular Weight: 172.269
• Mol file: 15057-22-4.mol

Synonyms:S,S,S-trimethylsulfonium methanesulfonate

Chemical Property of S,S,S-trimethylsulfonium methanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S,S,S-trimethylsulfonium methanesulfonate

There total 1 articles about S,S,S-trimethylsulfonium methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dimethylsulfide (75-18-3) + n-octyl dimethyl phosphate (87285-95-8) → monooctylphosphoric acid (3991-73-9) + S,S,S-trimethylsulfonium methanesulfonate (15057-22-4) + Phosphoric acid methyl ester octyl ester (137301-41-8)

Guidance literature:

With methanesulfonic acid; 1) 0 deg C, 2 min, 2) r.t., 24 h;

Reference yield:

methyl (E)-1-methyl-2-oxo-3-[4-(trifluoromethoxy)benzylidene]cyclopentane-1-carboxylate + S,S,S-trimethylsulfonium methanesulfonate (15057-22-4) → C17H17F3O4

Guidance literature:

S,S,S-trimethylsulfonium methanesulfonate; With sodium t-butanolate; In acetonitrile; for 0.5h; Inert atmosphere; Cooling with ice;

methyl (E)-1-methyl-2-oxo-3-[4-(trifluoromethoxy)benzylidene]cyclopentane-1-carboxylate; In acetonitrile; for 1.5h; Cooling with ice;

Reference yield:

methyl (E)-1-methyl-2-oxo-3-[4-(trifluoromethyl)benzylidene]cyclopentane-1-carboxylate + S,S,S-trimethylsulfonium methanesulfonate (15057-22-4) → C17H17F3O3

Guidance literature:

S,S,S-trimethylsulfonium methanesulfonate; With sodium t-butanolate; In acetonitrile; for 0.5h; Inert atmosphere; Cooling with ice;

methyl (E)-1-methyl-2-oxo-3-[4-(trifluoromethyl)benzylidene]cyclopentane-1-carboxylate; In acetonitrile; for 1h; Cooling with ice;

upstream raw materials:

dimethylsulfide

n-octyl dimethyl phosphate

Downstream raw materials:

2-(4-methylphenyl)oxirane

4-Chlorostyrene oxide

o-chlorostyrene oxide

2-methyl-2-phenyloxirane

Refernces