(C₅H₅)2TiCH₂SC₆H₄

Base Information

• Chemical Name: (C₅H₅)2TiCH₂SC₆H₄
• CAS No.: 84430-53-5
• Molecular Formula: C₁₇H₁₆STi
• Molecular Weight: 300.26
• Mol file: 84430-53-5.mol

Synonyms:(C₅H₅)2TiCH₂SC₆H₄

Chemical Property of (C₅H₅)2TiCH₂SC₆H₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (C₅H₅)2TiCH₂SC₆H₄

There total 1 articles about (C₅H₅)2TiCH₂SC₆H₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + racemic methyl phenyl sulfoxide (1193-82-4) → (C5H5)2TiCH2SC6H4 (84430-53-5) + bis(benzenethiolato)bis(η5-cyclopentadienyl)titanium + bis(phenylthio)methane (3561-67-9) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

With sodium amalgam; n-butyllithium; In tetrahydrofuran; hexane; byproducts: mercury; Cp2TiCl2 and Na/Hg stirred in THF for 2 h, after 2 h decanted, chilled to -78°C; 2 M BuLi/hexane added dropwise to PhS(O)Me in THF at 0°C, chilled to -78°C, added with stirring to soln. of (Cp2TiCl)2, warmed to room temp.; filtered, evapd. in vac., extd. with benzene, concd., chromd. (Al2O3, hexane/benzene), purified by sublimation at 130°C/0.1 mmHg; elem. anal.;

DOI:10.1016/S0022-328X(00)86902-8

Reference yield:

(C5H5)2TiCH2SC6H4 (84430-53-5) → bis(cyclopentadienyl)titanium dichloride (1271-19-8) + methyl-phenyl-thioether (100-68-5)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; Cp2TiCH2SC6H4 dissolved in dry de-gassed THF at room temp., dry HCl gasbubbled through soln. for 2 min; evapd. in vac., heated at 0.1 mmHg to 130°C in short path distn.app., residue washed with pentane and ether;

DOI:10.1016/S0022-328X(00)86902-8

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

racemic methyl phenyl sulfoxide

Downstream raw materials:

bis(cyclopentadienyl)titanium dichloride

methyl-phenyl-thioether

Refernces