3561-67-9 Usage
Description
Bis(phenylthio)methane (PhSCH2SPh) is a dithioether ligand that is characterized by its light yellow crystalline powder appearance. It is known for its ability to form coordination complexes with silver(I) salts and is involved in the synthesis of various compounds, including (-)-rasfonin.
Uses
Used in Chemical Synthesis:
Bis(phenylthio)methane is used as a dithioether ligand for the synthesis of dihydroxy thioethers, which are important intermediates in the production of various organic compounds.
Used in Coordination Chemistry:
In the field of coordination chemistry, Bis(phenylthio)methane is used as a ligand to form coordination complexes with silver(I) salts. These complexes have potential applications in various areas, such as catalysis and materials science.
Used in Pharmaceutical Synthesis:
Bis(phenylthio)methane plays a crucial role in the synthesis of (-)-rasfonin, a compound with potential pharmaceutical applications. Its involvement in the synthesis process highlights its importance in the development of new drugs and therapeutic agents.
Used in the Synthesis of Specific Compounds:
Bis(phenylthio)methane is also utilized in the synthesis of specific compounds such as [Cu4I4μ-PhS2CH2SPh2]n, [(η5-C5Me5)MCl2(η1-(PhS)2CH2)], and 6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactoheptodialdo-1,5-pyranose diphenyl dithioacetal. These compounds have potential applications in various industries, including pharmaceuticals, materials science, and chemical research.
Synthesis Reference(s)
Synthetic Communications, 19, p. 31, 1989 DOI: 10.1080/00397918908050949Synthesis, p. 447, 1975 DOI: 10.1055/s-1975-23797
Check Digit Verification of cas no
The CAS Registry Mumber 3561-67-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,5,6 and 1 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 3561-67:
(6*3)+(5*5)+(4*6)+(3*1)+(2*6)+(1*7)=89
89 % 10 = 9
So 3561-67-9 is a valid CAS Registry Number.
InChI:InChI=1/C13H12S2/c1-3-7-12(8-4-1)14-11-15-13-9-5-2-6-10-13/h1-10H,11H2
3561-67-9Relevant articles and documents
Scalable electrochemical reduction of sulfoxides to sulfides
Kong, Zhenshuo,Pan, Chao,Li, Ming,Wen, Lirong,Guo, Weisi
supporting information, p. 2773 - 2777 (2021/04/21)
A scalable reduction of sulfoxides to sulfides in a sustainable way remains an unmet challenge. This report discloses an electrochemical reduction of sulfoxides on a large scale (>10 g) under mild reaction conditions. Sulfoxides are activated using a substoichiometric amount of the Lewis acid AlCl3, which could be regeneratedviaa combination of inexpensive aluminum anode with chloride anion. This deoxygenation process features a broad substrate scope, including acid-labile substrates and drug molecules.
Consecutive C1-Homologation / Displacement Strategy for Converting Thiosulfonates into O,S-Oxothioacetals
Ielo, Laura,Pillari, Veronica,Miele, Margherita,Holzer, Wolfgang,Pace, Vittorio
, p. 5444 - 5449 (2020/10/12)
A conceptually intuitive synthesis of oxothioacetals is reported starting from thiosulfonates as electrophilic sulfur donors. The installation of a reactive CH2Cl motif with a homologating carbenoid reagent, followed by the immediate nucleophilic displacement with alcoholic groups [(hetero)-aromatic, aliphatic] offer a convenient access to the title compounds. Genuine chemoselectivity is uniformly observed in the case of multi-functionalized systems. (Figure presented.).
Reduction of CO2 into Methylene Coupled with the Formation of C-S Bonds under NaBH4/I2 System
Guo, Zhiqiang,Zhang, Bo,Wei, Xuehong,Xi, Chanjuan
, p. 6678 - 6681 (2018/10/24)
A selective four-electron reduction of CO2 with thiophenol using NaBH4 as a reductant is described to access dithioacetals. This reaction provides a novel synthetic method for the highly selective conversion of CO2 into methylene, and a new access to molecular structures via formation of C-S bonds using CO2 as the C1 source.
