2-PHENYL-1,3,2-DIOXABORINANE

Base Information

• Chemical Name: 2-PHENYL-1,3,2-DIOXABORINANE
• CAS No.: 4406-77-3
• Molecular Formula: C9H11 B O2
• Molecular Weight: 161.996
• Hs Code.: 2934999090
• Mol file: 4406-77-3.mol

Synonyms:Benzeneboronicacid, cyclic trimethylene ester (7CI,8CI); 1,3-Propanediol, cyclicbenzeneboronate (8CI); 1,3-Propylene benzeneboronate;2-Phenyl-1,3,2-dioxaborinane; Propane-1,3-diol phenylboronate

Chemical Property of 2-PHENYL-1,3,2-DIOXABORINANE

Chemical Property:

• Vapor Pressure: 0.00648mmHg at 25°C
• Refractive Index: n20/D 1.528(lit.)
• Boiling Point: 106 °C2 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 18.46000
• Density: 1.077 g/mL at 25 °C(lit.)
• LogP: 0.81870
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Phenyl-1,3,2-dioxaborinane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2-PHENYL-1,3,2-DIOXABORINANE

There total 13 articles about 2-PHENYL-1,3,2-DIOXABORINANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

trimethyleneglycol (504-63-2) + phenylboronic acid (98-80-6) → 2-Phenyl-1,3,2-dioxaborinane (4406-77-3)

Guidance literature:

In dichloromethane; at 20 ℃;

DOI:10.1021/ol300627p

Reference yield: 88.5%

2-phenyl[1,3,2]dioxaborolane (4406-72-8) + trimethyleneglycol (504-63-2) → 2-Phenyl-1,3,2-dioxaborinane (4406-77-3)

Guidance literature:

In chloroform-d1; byproducts: HOCH2CH2OH; inder inert atm., at 25°C, for 0.1 h, in NMR tube; monitoring by (1)H NMR; Kinetics;

DOI:10.1016/j.jorganchem.2006.10.013

Reference yield: 71.0%

→ 2-Phenyl-1,3,2-dioxaborinane (4406-77-3)

Guidance literature:

upstream raw materials:

triphenylboroxine

trimethyleneglycol

diphenyldiboronic acid

phenylboronic acid

Downstream raw materials:

4-methoxylbiphenyl

(Z)-(1-fluoro-2-phenylethenyl)benzene

(R)-(4-chlorophenyl)phenylmethanol

biphenyl

Refernces

• 1、 Salim Lew, Tedrick Thomas,Wen Lim, Diane Shu,Zhang, Yugen. "Copper(i)-catalyzed amidation reaction of organoboronic esters and isocyanates". supporting information. p. 5140 - 5143. Retrieved 2015/12/05.
• 2、 Dastbaravardeh, Navid,Schnuerch, Michael,Mihovilovic, Marko D.. "Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates". supporting information; experimental part. p. 1930 - 1933. Retrieved 2012/05/31.