N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Base Information

• Chemical Name: N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide
• CAS No.: 400779-99-9
• Molecular Formula: C₄₈H₃₆Br₂Cl₄N₂O₄
• Molecular Weight: 1006.44
• Mol file: 400779-99-9.mol

Synonyms:N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property of N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

There total 1 articles about N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.53%

4-bromo-2,6-diisopropylaniline (80058-84-0) + 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride (156028-26-1) → N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide (400779-99-9)

Guidance literature:

With propionic acid; for 17h; Heating / reflux;

Reference yield: 62.0%

p-hydroxyphenethyl alcohol (501-94-0) + N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide (400779-99-9) → N,N'-bis(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetra[4-(2-hydroxyethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide

Guidance literature:

With potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 90 ℃; for 12h;

Reference yield:

tert-octylphenol (140-66-9) + N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide (400779-99-9) → N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetra[4-(1,1,3,3-tetramethylbutyl)phenyloxy]perylene-3,4:9,10-tetracarboxylic acid bisimide

Guidance literature:

tert-octylphenol; N,N'-di(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide; With potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 90 ℃; for 12h;

With hydrogenchloride; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 2h;

DOI:10.1002/anie.200353621

upstream raw materials:

4-bromo-2,6-diisopropylaniline

1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Refernces

• 1、 -. "Functionalized perylene tetracarboxylic acid diimides". Page/Page column 13-14. . Retrieved 2010/02/12.