1,3-Diiodoperfluoropropane

Base Information

• Chemical Name: 1,3-Diiodoperfluoropropane
• CAS No.: 422-91-3
• Molecular Formula: C3F6 I2
• Molecular Weight: 403.832
• Hs Code.: 2903799090
• European Community (EC) Number: 875-882-0
• DSSTox Substance ID: DTXSID60448247
• Nikkaji Number: J666.602G
• Wikidata: Q82267222
• Mol file: 422-91-3.mol

Synonyms:1,3-Diiodoperfluoropropane;1,3-diiodohexafluoropropane;422-91-3;1,1,2,2,3,3-hexafluoro-1,3-diiodopropane;1, 3-Diiodoperfluoropropane;SCHEMBL52196;DTXSID60448247

Chemical Property of 1,3-Diiodoperfluoropropane

Chemical Property:

• Boiling Point: 131 °C
• PSA: 0.00000
• Density: 2.6302 g/cm3(Temp: 40 °C)
• LogP: 3.67730
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 403.79936
• Heavy Atom Count: 11
• Complexity: 138

Purity/Quality:

99%min ^*data from raw suppliers

1,3-DIIODOHEXAFLUOROPROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(F)(F)I)(C(F)(F)I)(F)F

Technology Process of 1,3-Diiodoperfluoropropane

There total 9 articles about 1,3-Diiodoperfluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

Tris(trifluormethyl)-difluorphosphoran (661-45-0,79549-41-0) + iodine (7553-56-2,12190-71-5,8031-47-8) → 1,1,2,2,3,3-hexafluoro-1,3-diiodopropane (422-91-3) + 1,2-diiodotetrafluoroethane (354-65-4) + difluorodiiodomethane (1184-76-5) + 1,1,2,2,3,3-Hexafluoro-cyclopropane (931-91-9)

Guidance literature:

ppyrolysis at 120°C (24 h);

Reference yield: 21.0%

hexafluoroglutaryl fluoride (678-78-4) → 1,1,2,2,3,3-hexafluoro-1,3-diiodopropane (422-91-3) + Perfluoro(4-iodobutanoyl) fluoride

Guidance literature:

With lithium iodide; at 180 ℃; for 7h;

DOI:10.1016/S0022-1139(97)00011-0

Reference yield:

1,1,2,2,3,3-Hexafluoro-cyclopropane (931-91-9) → 1,3-dichlorohexafluoropropane (662-01-1) + 1,1,2,2,3,3-hexafluoro-1,3-diiodopropane (422-91-3) + 1-chloro-1,1,2,2,3,3-hexafluoro-3-iodo-propane

Guidance literature:

With Iodine monochloride; at 230 ℃; for 10h;

DOI:10.1021/jo030014y

upstream raw materials:

Hexafluoropropene oxide

hexafluoroglutaryl fluoride

1,1,2,2,3,3-Hexafluoro-cyclopropane

perfluoro-3-phenoxypropylene oxide

Downstream raw materials:

α,ο-diphenylperfluoropropane

<3-Jod-perfluor-propyl>-benzol

1H-3-Phenyl-perfluor-propan

1,3-Bis-<3-nitro-phenyl>-perfluor-propan

Refernces

• 1、 -. "METHOD OF MAKING ALPHA, OMEGA-DIIODOPERFLUOROALKANES". Page/Page column 12-13. . Retrieved 2014/05/07.
• 2、 Yang, Zhen-Yu. "Preparation of highly fluorinated cyclopropanes and ring-opening reactions with halogens". . p. 4410 - 4416. Retrieved 2007/10/03.