sodium 2,2,2-trifluoroethanolate

Base Information

• Chemical Name: sodium 2,2,2-trifluoroethanolate
• CAS No.: 420-87-1
• Molecular Formula: C2H3 F3 O . Na
• Molecular Weight: 122.022
• Mol file: 420-87-1.mol

Synonyms:Ethanol,2,2,2-trifluoro-, sodium deriv. (6CI);Ethanol, 2,2,2-trifluoro-, sodium salt(8CI,9CI);Sodium, (2,2,2-trifluoroethoxy)- (7CI);2,2,2-Trifluoroethanolsodium salt;Sodium 2,2,2-trifluoroethanol;Sodium 2,2,2-trifluoroethanolate;Sodium 2,2,2-trifluoroethoxide;Sodium trifluoroethanol;Sodiumtrifluoroethoxide;Sodium trifluoroethylate;

Chemical Property of sodium 2,2,2-trifluoroethanolate

Chemical Property:

• Vapor Pressure: 77.3mmHg at 25°C
• Boiling Point: 74°Cat760mmHg
• Flash Point: 29.4°C
• PSA: 23.06000
• Density: g/cm³
• LogP: 0.97920

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium 2,2,2-trifluoroethanolate

There total 4 articles about sodium 2,2,2-trifluoroethanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,2-trifluoroethanol (75-89-8) → sodium 2,2,2-trifluoroethanolate (420-87-1)

Guidance literature:

With sodium hydrate; In diethyl ether;

DOI:10.1021/jo01313a008

Reference yield:

2,2,2-trifluoroethanol (75-89-8) + sodium hydride (7646-69-7) → sodium 2,2,2-trifluoroethanolate (420-87-1)

Guidance literature:

In tetrahydrofuran;

Reference yield:

trifluoroethanol (855719-15-2) + 3,5-bis(ethylsulfonyl)-4-cyanoisothiazole + benzylamine (100-46-9) → 3-(1,1,1-trifluoroethoxy)-4-cyano-5-benzylaminoisothiazole + sodium 2,2,2-trifluoroethanolate (420-87-1)

Guidance literature:

In N-methyl-acetamide;

upstream raw materials:

2,2,2-trifluoroethanol

trifluoroethanol

benzylamine

sodium hydride

Downstream raw materials:

1.1-Dicyano-2-p-dimethylaminophenyl-2-trifluorethoxyethylen

(Z)-2-Acetylamino-3-phenyl-acrylic acid 2,2,2-trifluoro-ethyl ester

7,7,7-trifluoro-1-phenyl-5-oxa-2-thiaheptane

1-nitro-3-(2,2,2-trifluoroethoxy)benzene

Refernces

• 1、 Hof, Ferdinand,Hauke, Frank,Hirsch, Andreas. "Brominated single walled carbon nanotubes as versatile precursors for covalent sidewall functionalization". . p. 6582 - 6584. Retrieved 2014.
• 2、 Bai, Wen-Long,Zhang, Zhen,Chen, Xin,Zhang, Qiang,Xu, Zhi-Xin,Zhai, Guang-Yao,Lin, Xiu,Liu, Xin,Tadesse Tsega, Tsegaye,Zhao, Chuan,Wang, Kai-Xue,Chen, Jie-Sheng. "Phosphazene-derived stable and robust artificial SEI for protecting lithium anodes of Li-O2batteries". supporting information. p. 12566 - 12569. Retrieved 2020/11/02.