1H,1H,2H,2H-Perfluorodecylamine

Base Information

• Chemical Name: 1H,1H,2H,2H-Perfluorodecylamine
• CAS No.: 30670-30-5
• Molecular Formula: C10H6 F17 N
• Molecular Weight: 463.137
• Hs Code.: 2921199090
• European Community (EC) Number: 812-132-3
• DSSTox Substance ID: DTXSID80382593
• Nikkaji Number: J25.758C
• Wikidata: Q82173953
• Mol file: 30670-30-5.mol

Synonyms:1H,1H,2H,2H-Perfluorodecylamine;30670-30-5;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecan-1-amine;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-decylamine;MFCD06248653;2-(Perfluorooctyl)ethylamine;C10H6F17N;SCHEMBL811215;DTXSID80382593;PFINVJYJNJHTFY-UHFFFAOYSA-N;BBL101879;STL555676;AKOS016015621;1-Decanamine, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-;1H,1H,2H,2H-Heptadecafluorodecylamine;s10636;CS-12221;SY040436;CS-0158339;FT-0677376;EN300-6732981;A820472;J-018048;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylamine

Chemical Property of 1H,1H,2H,2H-Perfluorodecylamine

Chemical Property:

• Vapor Pressure: 0.792mmHg at 25°C
• Refractive Index: 1.3
• Boiling Point: 182.9°Cat760mmHg
• PKA: 8.56±0.10(Predicted)
• Flash Point: 74.1°C
• PSA: 26.02000
• Density: 1.595g/cm³
• LogP: 6.04490
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Solubility.: Ethanol (Slightly), Methanol (Slightly)
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 8
• Exact Mass: 463.0228780
• Heavy Atom Count: 28
• Complexity: 559

Purity/Quality:

98%Min ^*data from raw suppliers

1H,1H,2H,2H-Perfluorodecylamine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CN)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 1H,1H,2H,2H-Perfluorodecylamine can be used as self-assembled monolayer (SAM) in organic LEDs

Technology Process of 1H,1H,2H,2H-Perfluorodecylamine

There total 4 articles about 1H,1H,2H,2H-Perfluorodecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-azido-1H,1H,2H,2H-perfluorodecane (121177-79-5) → 2-(perfluoro-n-octyl)ethylamine (30670-30-5)

Guidance literature:

With hydrogen; palladium on activated charcoal;

DOI:10.1016/j.bmcl.2005.11.107

Reference yield:

2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) → 2-(perfluoro-n-octyl)ethylamine (30670-30-5)

Guidance literature:

With ammonia; In butan-1-ol; at 80 ℃; for 3.5h;

DOI:10.1021/jm00347a012

Reference yield:

2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) + methyl-2-propen-3-ol (57642-98-5) → 2-(perfluoro-n-octyl)ethylamine (30670-30-5)

Guidance literature:

With sodium hydroxide; ammonia;

upstream raw materials:

2-(n-perfluorooctyl)ethyl iodide

1-azido-1H,1H,2H,2H-perfluorodecane

1-iodoheptadecafluorooctane

methyl-2-propen-3-ol

Downstream raw materials:

N-1H,1H,2H,2H-perfluorodecanebenzylamide

N-benzyl-N-1H,1H,2H,2H-perfluorodecane

N-(1H,1H,2H,2H-perfluorodecyl)-4,5-dimethyl-2-nitroaniline

C₂₆H₁₅F₁₇N₂O₄

Refernces

• 1、 Porcherie, Olivier,Guari, Yannick,Reye, Catherine. "Direct syntheses using a fluorinated surfactant of silicas containing organofluorinated groups". . p. 538 - 543. Retrieved 2005.
• 2、 Gaucher-Wieczorek, Florence S.,Maillard, Ludovic T.,Badet, Bernard,Durand, Philippe. "Fluorous tagged N-hydroxy phthalimide for the parallel synthesis of O-aryloxyamines". scheme or table. p. 655 - 658. Retrieved 2010/10/21.