4-chlorophenyl nonanate

Base Information

• Chemical Name: 4-chlorophenyl nonanate
• CAS No.: 1387574-39-1
• Molecular Formula: C₁₅H₂₁ClO₂
• Molecular Weight: 268.784
• Mol file: 1387574-39-1.mol

Synonyms:4-chlorophenyl nonanate

Chemical Property of 4-chlorophenyl nonanate

Chemical Property:

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Technology Process of 4-chlorophenyl nonanate

There total 7 articles about 4-chlorophenyl nonanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

4-chlorophenyl 4-(tert-butyl)phenylbenzoate (314046-46-3) + octyl p-cyanophenylmethyl ketone (1387574-33-5) → 4-chlorophenyl nonanate (1387574-39-1) + 4-[2-[4-(1,1-dimethylethyl)phenyl]-2-oxoethyl]benzonitrile (727722-43-2)

Guidance literature:

With RhH(CO)(PPh₃)3; o-phenylenebis(diphenylphosphine); In 1,3-dimethyl-2-imidazolidinone; at 150 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol3017148

Reference yield: 46.0%

octyl p-cyanophenylmethyl ketone (1387574-33-5) + 4-chlorophenyl 4-methoxybenzoate (29558-84-7) → 4-chlorophenyl nonanate (1387574-39-1) + 4-[2-(4-methoxyphenyl)-2-oxoethyl]benzonitrile (62066-32-4)

Guidance literature:

With RhH(CO)(PPh₃)3; o-phenylenebis(diphenylphosphine); In 1,3-dimethyl-2-imidazolidinone; at 150 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol3017148

Reference yield: 39.0%

4-chlorophenyl 4-chlorobenzoate (6961-42-8) + octyl p-cyanophenylmethyl ketone (1387574-33-5) → 4-chlorophenyl nonanate (1387574-39-1) + 4-[2-(4-chlorophenyl)-2-oxoethyl]benzonitrile (62066-31-3)

Guidance literature:

With RhH(CO)(PPh₃)3; o-phenylenebis(diphenylphosphine); In 1,3-dimethyl-2-imidazolidinone; at 150 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol3017148

upstream raw materials:

4-chlorophenyl 4-(tert-butyl)phenylbenzoate

octyl p-cyanophenylmethyl ketone

4-chlorophenyl 4-chlorobenzoate

4-chlorophenyl 4-methoxybenzoate

Refernces