Technology Process of tricyclohexyldocosyltin
There total 2 articles about tricyclohexyldocosyltin which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-butyllithium; diisopropylamine;
In
tetrahydrofuran; hexane;
byproducts: LiBr; (N2); using Schlenk techniques; addn. of n-BuLi/hexane to (i-Pr)2NH in THF at 0°C; stirring for 15 min at this temp.; addn. of soln. of SnHCy3 in THF; stirring for 0.5h; addn. of BrC22H45/THF at 0°C; warming to room temp.; stirring for 20h; treatment with satd. NH4Cl; extn. into petroleum ether; washing of org. phases with H2O; drying over MgSO4; evapn. of solvent; recrystn. from absolute EtOH; elem. anal.;
DOI:10.1021/om700534j
- Guidance literature:
-
With
azobis(isobutyronitrile);
In
neat (no solvent);
(N2); using Schlenk techniques; heating of docos-1-ene with SnCy3H in the presence of azobis(isobutyronitrile) at 110°C;
DOI:10.1021/om700534j
