4-METHYL-1,2-CYCLOHEXENE OXIDE

Base Information

• Chemical Name: 4-METHYL-1,2-CYCLOHEXENE OXIDE
• CAS No.: 36099-51-1
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.172
• Hs Code.: 2932999099
• Mol file: 36099-51-1.mol

Synonyms:7-Oxabicyclo[4.1.0]heptane,4-methyl- (6CI); 3-Methyl-7-oxabicyclo[4.1.0]heptane; 4-Methylcyclohexene oxide

Chemical Property of 4-METHYL-1,2-CYCLOHEXENE OXIDE

Chemical Property:

• Vapor Pressure: 7.39mmHg at 25°C
• Refractive Index: 1.463
• Boiling Point: 141.2°Cat760mmHg
• Flash Point: 26.7°C
• PSA: 12.53000
• Density: 0.964g/cm³
• LogP: 1.57380

Purity/Quality:

99% ^*data from raw suppliers

4-METHYL-1,2-CYCLOHEXENE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-METHYL-1,2-CYCLOHEXENE OXIDE

There total 3 articles about 4-METHYL-1,2-CYCLOHEXENE OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

4-methylcyclohexene (591-47-9) → 3-methyl-7-oxabicyclo[4.1.0]heptane (36099-51-1,103189-46-4,103189-47-5) + 5-methylcyclohex-2-en-1-one (7214-50-8) + 4-methyl-2-cyclohexenone (75337-05-2,79980-78-2,101758-35-4,5515-76-4) + Methyl-2-cyclohexen-1-ol (21592-97-2) + 5-methyl-2-cyclohexen-1-ol (3718-55-6)

Guidance literature:

With 6C₁₆H₃₆N⁽¹⁺⁾*2Zn⁽²⁺⁾*4Na⁽¹⁺⁾*[Bi₂Zn₂(ZnW₉O₃₄)2]^(14-); urea hydrogen peroxide adduct; In acetonitrile; at 70 ℃; for 24h;

DOI:10.1021/acscatal.5b00066

Reference yield: 10.0%

4-methylcyclohexene (591-47-9) → 3-methyl-7-oxabicyclo[4.1.0]heptane (36099-51-1,103189-46-4,103189-47-5) + 5-methylcyclohex-2-en-1-one (7214-50-8) + 6-methylcyclohex-2-en-1-one (6610-21-5)

Guidance literature:

With iodoxybenzene; bis(acetylacetonate)oxovanadium; In benzene; for 4h; Product distribution; Heating;

Reference yield:

4-methylcyclohexene (591-47-9) → 3-methyl-7-oxabicyclo[4.1.0]heptane (36099-51-1,103189-46-4,103189-47-5) + 1,2-dihydroxy-4-methylcyclohexane (23832-27-1)

Guidance literature:

With dihydrogen peroxide; In water; acetonitrile; at 59.84 ℃; for 2h;

DOI:10.1039/c3gc42534g

upstream raw materials:

4-methylcyclohexene

Downstream raw materials:

2,5-dimethylcyclohexanol

menthol

3-methyl-7-thia-norcarane

(+/-)-1ξ-methyl-cyclohexanediol-(3r.4t)

Refernces

• 1、 Tang, Bo,Dai, Weili,Sun, Xiaoming,Guan, Naijia,Li, Landong,Hunger, Michael. "A procedure for the preparation of Ti-Beta zeolites for catalytic epoxidation with hydrogen peroxide". . p. 2281 - 2291. Retrieved 2014/04/17.