Benzyln-butylether

Base Information

• Chemical Name: Benzyln-butylether
• CAS No.: 3459-80-1
• Molecular Formula: C11H16 O
• Molecular Weight: 164.247
• Hs Code.: 2909309090
• Mol file: 3459-80-1.mol

Synonyms:Ether,benzyl tert-butyl (7CI,8CI); 2-Benzyloxy-2-methylpropane; Benzyl tert-butylether; [(1,1-Dimethylethoxy)methyl]benzene

Chemical Property of Benzyln-butylether

Chemical Property:

• Vapor Pressure: 0.383mmHg at 25°C
• Refractive Index: 1.488
• Boiling Point: 204.1°C at 760 mmHg
• Flash Point: 75.1°C
• PSA: 9.23000
• Density: 0.921g/cm³
• LogP: 3.00170

Purity/Quality:

98% ^*data from raw suppliers

BENZYL TERT-BUTYL ETHER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of Benzyln-butylether

There total 50 articles about Benzyln-butylether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

benzyl alcohol (100-51-6,185532-71-2) + tert-butyl alcohol (75-65-0) → t-butoxymethylbenzene (3459-80-1)

Guidance literature:

With sulfuric acid; magnesium sulfate; In dichloromethane; at 25 ℃; for 18h;

DOI:10.1016/S0040-4039(97)01792-9

Reference yield: 50.0%

benzyl alcohol (100-51-6,185532-71-2) + tert-butyl alcohol (75-65-0) → 2,2'-oxybis(2-methyl-propane) (6163-66-2) + t-butoxymethylbenzene (3459-80-1) + dibenzyl ether (103-50-4)

Guidance literature:

With copper(ll) bromide; at 175 ℃; for 10h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube;

DOI:10.1134/S1070428018080055

Reference yield: 32.0%

tert-butoxytrimethylsilane (13058-24-7) + benzaldehyde (100-52-7) → t-butoxymethylbenzene (3459-80-1) + dibenzyl ether (103-50-4)

Guidance literature:

With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; 0 deg C -> r.t.;

DOI:10.1016/S0040-4039(00)73357-0

upstream raw materials:

isobutene

benzyl alcohol

potassium tert-butylate

benzyl chloride

Downstream raw materials:

3-phenyl-2-quinoxalinecarbonitrile

3-phenylquinoxaline-2-carbonitrile 1,4-dioxide

benzo[d]oxazol-2-yl(phenyl)methanone

2-benzoylbenzothiazole

Refernces

• 1、 Cui, Xinjiang,Zhang, Shiguo,Shi, Feng,Zhang, Qinghua,Ma, Xiangyuan,Lu, Liujin,Deng, Youquan. "The influence of the acidity of ionic liquids on catalysis". . p. 1043 - 1047. Retrieved 2010.
• 2、 Blake, Finn,Leyva-Pérez, Antonio,Sanz-Navarro, Sergio,Tejeda-Serrano, María. "Zeolites Catalyze the Nazarov Reaction and the tert -Butylation of Alcohols by Stabilization of Carboxonium Intermediates". . p. 2031 - 2037. Retrieved 2020/07/14.
• 3、 Shang, Yuhan,Zheng, Mai,Zhang, Haibo,Zhou, Xiaohai. "The Guanidine-Promoted Direct Synthesis of Open-Chained Carbonates". . p. 933 - 938. Retrieved 2019/09/30.