tert-Butoxytrimethylsilane

Base Information

• Chemical Name: tert-Butoxytrimethylsilane
• CAS No.: 13058-24-7
• Molecular Formula: C7H18OSi
• Molecular Weight: 146.305
• Hs Code.: 2931900090
• Mol file: 13058-24-7.mol

Synonyms:Silane, tert-butoxytrimethyl-;

Chemical Property of tert-Butoxytrimethylsilane

Chemical Property:

• Vapor Pressure: 36.1mmHg at 25°C
• Melting Point: -91°C
• Refractive Index: 1.3913
• Boiling Point: 104.258 °C at 760 mmHg
• Flash Point: -0.585 °C
• PSA: 9.23000
• Density: 0.786 g/cm³
• LogP: 2.63640

Purity/Quality:

99% ^*data from raw suppliers

tert-Butoxytrimethylsilane ^*data from reagent suppliers

Safty Information:

• Statements: 12-20/21/22
• Safety Statements: 9-16-33

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-Butoxytrimethylsilane

There total 51 articles about tert-Butoxytrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1,1-trimethyl-2,2,2-triphenyldisilane (1450-18-6) → tert-butoxytrimethylsilane (13058-24-7) + triphenylsilylkalium (15487-82-8,6735-25-7)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 24h;

DOI:10.1016/0022-328X(92)83433-I

Reference yield: 95.0%

1,1,1-trimethyl-2,2,2-triphenyldisilane (1450-18-6) + potassium tert-butylate (865-47-4) → tert-butoxytrimethylsilane (13058-24-7) + triphenylsilylkalium (15487-82-8,6735-25-7)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 24h;

DOI:10.1016/0022-328X(92)83433-I

Reference yield: 91.0%

3-(trimethylsilyl)-2-oxazolidinone (43112-38-5) + tert-butyl alcohol (75-65-0) → dimethylenecyclourethane (497-25-6) + tert-butoxytrimethylsilane (13058-24-7)

Guidance literature:

trifluorormethanesulfonic acid; at 15 ℃; for 0.00416667h;

upstream raw materials:

chloro-trimethyl-silane

tert-butyl alcohol

O,O-diethyl α-trimethylsilylbenzylphosphonate

potassium tert-butylate

Downstream raw materials:

ethyl trimethylsilyl ether

Hexamethyldisiloxane

Ethylene glycol di-tert-butyl diether

trimethylsilyl formate

Refernces

• 1、 Voss et al.. "". . p. 219,221. Retrieved 1978.
• 2、 Bl?sing, Kevin,Labbow, Rene,Schulz, Axel,Villinger, Alexander. "Silylated Sulfuric Acid: Preparation of a Tris(trimethylsilyl)oxosulfonium [(Me3Si?O)3SO]+ Salt". . p. 13798 - 13802. Retrieved 2021.
• 3、 Nikbakht, Fatemeh,Ghonchepour, Ehsan,Ziyadi, Hakimeh,Heydari, Akbar. "Tributyltin grafted onto the surface of 3-aminopropyl functionalized γ-Fe2O3 nanoparticles: A magnetically-recoverable catalyst for trimethylsilylation of alcohols and phenols". . p. 34428 - 34434. Retrieved 2014.
• 4、 Hopper et al.. "". . p. 173,177-179. Retrieved 1977.
• 5、 Lange, Heike,Herzog, Uwe. "Bis(oligosilanyl)chalcogenides [Me3Si)xMe3-xSi]2E, alkalimetal oligosilanylchalcogenolates (Me3Si)xMe3-xSi-EMI and oligosilanylchalcogenols (Me3Si)xMe3-xSi-EH (E = S, Se, Te) syntheses and NMR study". . p. 36 - 42. Retrieved 2002.
• 6、 Dey, Rupa R.,Paul, Bappi,Dhar, Siddhartha S.,Bhattacharjee, Sushmita. "Novel protocol for the synthesis of organic ammonium tribromides and investigation of 1,1′-(Ethane-1,2-diyl)dipiperidinium bis(tribromide) in the silylation of alcohols and thiols". . p. 1545 - 1547. Retrieved 2014.
• 7、 Comas-Vives, Aleix,Eiler, Frederik,Grützmacher, Hansj?rg,Pribanic, Bruno,Trincado, Monica,Vogt, Matthias. "Hydrogenolysis of Polysilanes Catalyzed by Low-Valent Nickel Complexes". supporting information. p. 15603 - 15609. Retrieved 2020/04/29.