2-chloro-2-nitroso-1,3-diphenylpropane

Base Information

• Chemical Name: 2-chloro-2-nitroso-1,3-diphenylpropane
• CAS No.: 101102-91-4
• Molecular Formula: C₁₅H₁₄ClNO
• Molecular Weight: 259.735
• Mol file: 101102-91-4.mol

Synonyms:2-chloro-2-nitroso-1,3-diphenylpropane

Chemical Property of 2-chloro-2-nitroso-1,3-diphenylpropane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-chloro-2-nitroso-1,3-diphenylpropane

There total 3 articles about 2-chloro-2-nitroso-1,3-diphenylpropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,3-diphenylpropan-2-one oxime (1788-31-4) → 2-chloro-2-nitroso-1,3-diphenylpropane (101102-91-4)

Guidance literature:

With chloro-trimethyl-silane; isopentyl nitrite; In diethyl ether; at -10 ℃; for 1.25h;

DOI:10.1007/s12039-011-0090-7

Reference yield: 43.0%

1,3-diphenylpropan-2-one oxime (1788-31-4) → 2-chloro-2-nitroso-1,3-diphenylpropane (101102-91-4) + 2-chloro-2-nitro-1,3-diphenylpropane

Guidance literature:

With chloro-trimethyl-silane; nitro acetate; In dichloromethane; at -10 ℃;

DOI:10.1007/s12039-010-0091-y

Reference yield:

→ 2-chloro-2-nitroso-1,3-diphenylpropane (101102-91-4)

Guidance literature:

Dibenzylketoxim, Chlor einleiten, (alkal. oder neutrale Lsg.);

upstream raw materials:

1,3-diphenylpropan-2-one oxime

Downstream raw materials:

1,1'-[(1E/Z)-2-chloro-1-propene-1,3-diyl]bisbenzene

1,3-Diphenylpropanone

Refernces

• 1、 Mohammed, Abdulkarim H. A.,Nagendrappa, Gopalpur. "Generation of nitryl chloride from chlorotrimethylsilane-acetyl nitrate reaction: A one-pot preparation of gem-chloronitro compounds from oximes". experimental part. p. 571 - 577. Retrieved 2010/12/20.