bis(4-anisyl)iodonium triflate

Base Information

• Chemical Name: bis(4-anisyl)iodonium triflate
• CAS No.: 141339-54-0
• Molecular Formula: CF₃O₃S*C₁₄H₁₄IO₂
• Molecular Weight: 490.239
• Mol file: 141339-54-0.mol

Synonyms:bis(4-anisyl)iodonium triflate

Chemical Property of bis(4-anisyl)iodonium triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-anisyl)iodonium triflate

There total 10 articles about bis(4-anisyl)iodonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

trifluorormethanesulfonic acid (1493-13-6) + methoxybenzene (100-66-3) → bis(4-anisyl)iodonium triflate (141339-54-0)

Guidance literature:

methoxybenzene; With iodine; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.25h; Inert atmosphere;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 1h;

DOI:10.1002/anie.201004704

Reference yield: 71.0%

bis(4-methoxyphenyl)iodonium 4-methylbenzenesulfonate + trifluorormethanesulfonic acid (1493-13-6) → bis(4-anisyl)iodonium triflate (141339-54-0)

Guidance literature:

In dichloromethane; water; at 20 ℃; for 1h;

DOI:10.1055/s-2008-1032050

Reference yield: 71.0%

(p-methoxyphenyl)tri-n-butylstannane (70744-47-7) + di(cyano)iodonium triflate (141339-50-6) → bis(4-anisyl)iodonium triflate (141339-54-0)

Guidance literature:

In dichloromethane; at -40 - 20 ℃;

DOI:10.1016/S0040-4039(00)91636-8

upstream raw materials:

(p-methoxyphenyl)tri-n-butylstannane

di(cyano)iodonium triflate

trifluorormethanesulfonic acid

4-methoxy(diacetoxyiodo)benzene

Downstream raw materials:

N-(4-methoxyphenyl)-S,S-dimethylsulfoximine

N-(4-methoxyphenyl)-S,S-diphenylsulfoximine

(±)-((4-methoxyphenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone

5-(4-methoxyphenyl)-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine

Refernces

• 1、 Huang, Xiao-Ling,Li, Chong,Wang, Juan,Yang, Shang-Dong. "Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles". supporting information. . Retrieved 2021/10/25.
• 2、 Das, Mrinmoy,Lee, Jiande,Liu, Xue-Wei,Pal, Kumar Bhaskar. "Palladium(ii)-catalyzed stereoselective synthesis of: C-glycosides from glycals with diaryliodonium salts". supporting information. p. 2242 - 2251. Retrieved 2020/04/07.