DIPHENYLIODIUM FLUORIDE

Base Information

• Chemical Name: DIPHENYLIODIUM FLUORIDE
• CAS No.: 322-23-6
• Molecular Formula: C12H10 I . F
• Molecular Weight: 300.114
• Hs Code.: 2903999090
• Mol file: 322-23-6.mol

Synonyms:Diphenyliodoniumfluoride (6CI); Iodonium, diphenyl-, fluoride (8CI,9CI)

Chemical Property of DIPHENYLIODIUM FLUORIDE

Chemical Property:

• Melting Point: 85 °C (decomp)
• PSA: 0.00000
• LogP: -3.18100

Purity/Quality:

98%min ^*data from raw suppliers

DIPHENYLIODIUM FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIPHENYLIODIUM FLUORIDE

There total 4 articles about DIPHENYLIODIUM FLUORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

diphenyliodonium nitrate (722-56-5) → Diphenyliodonium fluoride (322-23-6)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 1h; Inert atmosphere;

DOI:10.1016/j.jfluchem.2010.04.004

Reference yield: 56.0%

diphenyliodonium iodide (2217-79-0) → Diphenyliodonium fluoride (322-23-6)

Guidance literature:

diphenyliodonium iodide; With silver(l) oxide; In water; at 0 - 20 ℃; for 11h;

With hydrogen fluoride; In water;

DOI:10.1002/chem.201604803

Reference yield:

phenyl(4-bromophenyl)iodonium hexafluorophosphate → C12H9BrI(1+)*F(1-) + C12H8Br2I(1+)*F(1-) + Diphenyliodonium fluoride (322-23-6)

Guidance literature:

With tetramethylammonium fluoride; In benzene-d6; Darkness;

DOI:10.1016/j.jfluchem.2010.04.004

upstream raw materials:

diphenyliodonium nitrate

4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride

diphenyliodonium iodide

Downstream raw materials:

(4-methoxy-phenyl)-phenyl-iodonium ; fluoride

fluorobenzene

((((R)-1-(6-amino-9H-purin-9-yl)propan-2-yl)oxy)methyl)phosphoric acid monophenyl ester

Refernces

• 1、 Wang, Bijia,Cerny, Ronald L.,Uppaluri, Shriharsha,Kempinger, Jayson J.,Dimagno, Stephen G.. "Fluoride-promoted ligand exchange in diaryliodonium salts". scheme or table. p. 1113 - 1121. Retrieved 2011/02/25.