Technology Process of Bis(pentafluorophenyl)diazomethane
There total 4 articles about Bis(pentafluorophenyl)diazomethane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium tert-butylate;
In
tetrahydrofuran;
at 60 ℃;
for 0.0166667h;
DOI:10.1021/jo00077a040
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 83.3 percent / SOCl2, pyridine / 2 h / Heating
2: 23 percent / AgBF4 / dioxane / 2 h / 80 °C
3: NaNO2 / acetic acid; acetic anhydride / 0 °C
4: 11.2 percent / t-BuOK / tetrahydrofuran / 0.02 h / 60 °C
With
pyridine; silver tetrafluoroborate; thionyl chloride; potassium tert-butylate; sodium nitrite;
In
tetrahydrofuran; 1,4-dioxane; acetic anhydride; acetic acid;
DOI:10.1021/jo00077a040
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 23 percent / AgBF4 / dioxane / 2 h / 80 °C
2: NaNO2 / acetic acid; acetic anhydride / 0 °C
3: 11.2 percent / t-BuOK / tetrahydrofuran / 0.02 h / 60 °C
With
silver tetrafluoroborate; potassium tert-butylate; sodium nitrite;
In
tetrahydrofuran; 1,4-dioxane; acetic anhydride; acetic acid;
DOI:10.1021/jo00077a040
