silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Base Information

• Chemical Name: silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
• CAS No.: 160298-76-0
• Molecular Formula: Ag*C₃₂H₁₂BF₂₄
• Molecular Weight: 971.088
• Mol file: 160298-76-0.mol

Synonyms:silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Chemical Property of silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

There total 3 articles about silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

silver nitrate + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (160298-76-0)

Guidance literature:

In diethyl ether; for 0.0833333h; Darkness;

DOI:10.1021/jacs.9b01862

Reference yield: 41.0%

silver tetrafluoroborate (14104-20-2) + 3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (160298-76-0)

Guidance literature:

With magnesium; In diethyl ether; Mg turnings were stirred in ether, the bromobenzene was added at room temp., heated to reflux for 30 min, cooled to room temp., AgBF4 was added,mixt. was stirred for 60 h; mixt. was poured into aq. Na2CO3 soln., filtered, aq. layer was sepd. and extd. with ether, extracts were combined, solvent was removed, solid was washed with cold CH2Cl2, dried in vac.;

DOI:10.1021/om0103097

Reference yield:

silver nitrate + potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (105560-52-9) → silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (160298-76-0)

Guidance literature:

In not given; (Ar);

DOI:10.1039/b414060e

upstream raw materials:

potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

silver tetrafluoroborate

3,6-bis(trifluoromethyl)bromobenzene

Refernces

• 1、 Wang, Xiang,Shyshov, Oleksandr,Han?eva?ki, Marko,J?ger, Christof M.,Von Delius, Max. "Ammonium Complexes of Orthoester Cryptands Are Inherently Dynamic and Adaptive". . p. 8868 - 8876. Retrieved 2019.
• 2、 Zeng, Jing,Wang, Ruobin,Zhang, Shuxin,Fang, Jing,Liu, Shanshan,Sun, Guangfei,Xu, Bingbing,Xiao, Ying,Fu, Dengxian,Zhang, Wenqi,Hu, Yixin,Wan, Qian. "Hydrogen-Bonding-Assisted Exogenous Nucleophilic Reagent Effect for β-Selective Glycosylation of Rare 3-Amino Sugars". supporting information. p. 8509 - 8515. Retrieved 2019/06/13.