Fe₂(CO)8^(2-)

Base Information

• Chemical Name: Fe₂(CO)8^(2-)
• CAS No.: 58281-28-0
• Molecular Formula: C₈Fe₂O₈
• Molecular Weight: 335.777
• Mol file: 58281-28-0.mol

Synonyms:Fe₂(CO)8^(2-)

Chemical Property of Fe₂(CO)8^(2-)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Fe₂(CO)8^(2-)

There total 2 articles about Fe₂(CO)8^(2-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

iron(III)-acetylacetonate (14024-18-1) → iron pentacarbonyl (13463-40-6,37220-42-1) + Fe2(CO)8(2-) (58281-28-0)

Guidance literature:

With carbon monoxide; lithium perchlorate; In methanol; Electrochem. Process; the solid starting complex is placed in an electrolysis autoclave, the solvent is added under N2, the autoclave is closed, further bubbling of N2 for 30 min, then CO is pressed into the vessel (100 bar), electrolysis (LiClO4, 293 K, 60 mA, 1.0 V, 195 h);

Reference yield:

iron (7439-89-6) → iron pentacarbonyl (13463-40-6,37220-42-1) + Fe2(CO)8(2-) (58281-28-0) + Fe4(2-)*13CO=[Fe4(CO)13](2-)

Guidance literature:

With carbon monoxide; tetrabutylammomium bromide; In pyridine; Electrochem. Process; CO 1 bar, electrolysis (Fe-anode, Bu4NBr, 293 K, 30 mA, 4.5 V, 51 h);

upstream raw materials:

iron

iron(III)-acetylacetonate

Refernces