N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide

Base Information

• Chemical Name: N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide
• CAS No.: 1131544-86-9
• Molecular Formula: C₁₅H₁₇NP*I
• Molecular Weight: 369.185
• Mol file: 1131544-86-9.mol

Synonyms:N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide

Chemical Property of N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide

There total 5 articles about N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(diphenylphosphoryl)(N,N-dimethylamino)chloromethane (1352709-73-9) → N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide (1131544-86-9)

Guidance literature:

With triphenylphosphine; sodium iodide; In N,N-dimethyl-formamide; at 20 ℃; for 5h; Inert atmosphere;

DOI:10.1134/S1070363211100094

Reference yield: 72.0%

chloro-diphenylphosphine (1079-66-9,74391-44-9) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide (1131544-86-9)

Guidance literature:

With triphenylphosphine; sodium iodide; at 20 ℃; for 10h; Inert atmosphere;

DOI:10.1134/S1070363210010123

Reference yield: 41.0%

chloro-diphenylphosphine (1079-66-9,74391-44-9) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → N,N-dimethyl-(diphenylphosphinomethylene)iminium iodide (1131544-86-9) + diphenyl-phosphinic acid (1707-03-5)

Guidance literature:

chloro-diphenylphosphine; N,N-dimethyl-formamide; With sodium iodide; at 20 ℃; for 10h; Inert atmosphere;

With water; In dichloromethane; at 20 ℃;

DOI:10.1134/S1070363210010123

upstream raw materials:

chloro-diphenylphosphine

N,N-dimethyl-formamide

(diphenylphosphoryl)(N,N-dimethylamino)chloromethane

Refernces

• 1、 Morgalyuk,Petrovskii,Lysenko,Nifant'Ev. "Stoichiometry of the reaction of diphenylchlorophosphine with dimethylformamide in the presence of NaI". experimental part. p. 100 - 105. Retrieved 2010/05/01.