5,10,15,20-tetraphenylporphyrinato cadmium(II)

Base Information

• Chemical Name: 5,10,15,20-tetraphenylporphyrinato cadmium(II)
• CAS No.: 14977-07-2
• Molecular Formula: C₄₄H₂₈CdN₄
• Molecular Weight: 725.143
• Mol file: 14977-07-2.mol

Synonyms:5,10,15,20-tetraphenylporphyrinato cadmium(II)

Chemical Property of 5,10,15,20-tetraphenylporphyrinato cadmium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetraphenylporphyrinato cadmium(II)

There total 13 articles about 5,10,15,20-tetraphenylporphyrinato cadmium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.5%

cadmium(II) acetate (543-90-8) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetraphenylporphyrinato cadmium(II) (14977-07-2)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; at 120 ℃; for 1h; Inert atmosphere;

DOI:10.1002/cplu.201300143

Reference yield: 81.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) + cadmium(II) chloride (10108-64-2) → 5,10,15,20-tetraphenylporphyrinato cadmium(II) (14977-07-2)

Guidance literature:

In N,N-dimethyl-formamide; at 158 ℃;

DOI:10.1134/S1070363216010187

Reference yield: 71.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + cadmium(II) acetate dihydrate (5743-04-4) → 5,10,15,20-tetraphenylporphyrinato cadmium(II) (14977-07-2)

Guidance literature:

In N,N-dimethyl-formamide; cadmium acetate dihydrate with tetraphenylporphin was refluxed in DMF under N2 for 15 min; pptn. was washed with n-hexane, crystd. from methanol/CH2Cl2;

DOI:10.1039/c39800000492

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

cadmium(II) acetate

cadmium(II) acetate dihydrate

{CdC₄₄H₂₈N₄}*C₅H₅N

Downstream raw materials:

Cd(TPP)(dimethyl sulfoxide)

(tetraphenylporphyrin)copper(II)

zinc tetraphenylporphyrin

Cd(tetraphenylporphyrin)(pyridine)

Refernces

• 1、 Liang, Yu,Bradler, Maximilian,Klinger, Melanie,Schalk, Oliver,Balaban, Mihaela Carmen,Balaban, Teodor Silviu,Riedle, Eberhard,Unterreiner, Andreas-Neil. "Ultrafast dynamics of meso-tetraphenylmetalloporphyrins: The role of dark states". . p. 1244 - 1251. Retrieved 2013/11/06.
• 2、 Mamardashvili,Berezin. "Interaction of porphyrins with adenine and adenosine complexes. Effect of a metal nature". . p. 276 - 281. Retrieved 2008/10/09.