benzo[d][1,3]dioxol-5-yl(phenyl)methanimine

Base Information

• Chemical Name: benzo[d][1,3]dioxol-5-yl(phenyl)methanimine
• CAS No.: 857550-36-8
• Molecular Formula: C₁₄H₁₁NO₂
• Molecular Weight: 225.247
• Mol file: 857550-36-8.mol

Synonyms:benzo[d][1,3]dioxol-5-yl(phenyl)methanimine

Chemical Property of benzo[d][1,3]dioxol-5-yl(phenyl)methanimine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of benzo[d][1,3]dioxol-5-yl(phenyl)methanimine

There total 1 articles about benzo[d][1,3]dioxol-5-yl(phenyl)methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

piperonylonitrile (4421-09-4) → benzo[d][1,3]dioxol-5-yl(phenyl)methanimine (857550-36-8)

Guidance literature:

With phenylmagnesium bromide;

Reference yield: 83.0%

benzo[d][1,3]dioxol-5-yl(phenyl)methanimine (857550-36-8) + ethenyltrimethylsilane (754-05-2) → (4,6-bis(2-(trimethylsilyl)ethyl)benzo[d][1,3]dioxol-5-yl)(2,6-bis(2-(trimethylsilyl)ethyl)phenyl)methanimine

Guidance literature:

With pyridine; tris(3-fluorophenyl)phosphine; neopentylmagnesium bromide; cobalt(II) aceylacetonate; In tetrahydrofuran; at 20 ℃; for 12h; Schlenk technique;

DOI:10.1002/anie.201605877

Reference yield: 74.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + benzo[d][1,3]dioxol-5-yl(phenyl)methanimine (857550-36-8) → (4-phenethylbenzo[d][1,3]dioxol-5-yl)(phenyl)methanimine

Guidance literature:

With tri(m-chlorophenyl)-phosphine; neopentylmagnesium bromide; cobalt acetylacetonate; In tetrahydrofuran; at 20 ℃; for 12h; Schlenk technique; Inert atmosphere; Cooling with ice;

DOI:10.1021/acs.orglett.8b00164

upstream raw materials:

piperonylonitrile

Downstream raw materials:

(3,4-methylenedioxyphenyl) phenyl methanone