MeNH=BCy₂

Base Information

• Chemical Name: MeNH=BCy₂
• CAS No.: 1347747-76-5
• Molecular Formula: C₁₃H₂₆BN
• Molecular Weight: 207.167
• Mol file: 1347747-76-5.mol

Synonyms:MeNH=BCy₂

Chemical Property of MeNH=BCy₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of MeNH=BCy₂

There total 6 articles about MeNH=BCy₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

MeNH2-BH2-NHMe-BH3 (1314251-72-3) + cyclohexene (110-83-8) → MeNH=BCy2 (1347747-76-5)

Guidance literature:

In tetrahydrofuran; at 55 ℃; for 20h; Inert atmosphere;

DOI:10.1021/ja208752w

Reference yield:

Me3N-BH2-NHMe-BH3 (1349095-84-6) + cyclohexene (110-83-8) → (methylamino)dihydroborane (6601-31-6) + trimethylamine-borane (75-22-9) + MeNH=BCy2 (1347747-76-5) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

In tetrahydrofuran; at 70 ℃; for 18h; Inert atmosphere;

DOI:10.1021/ja404247r

Reference yield:

methylamine-borane (1722-33-4) + cyclohexene (110-83-8) → MeNH=BCy2 (1347747-76-5)

Guidance literature:

With diisopropopylaminoborane; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1021/ja208752w

upstream raw materials:

MeNH₂-BH₂-NHMe-BH₃

cyclohexene

methylamine-borane

Me₃N-BH₂-NHMe-BH₃

Refernces

• 1、 Johnson, Heather C.,Leitao, Erin M.,Whittell, George R.,Manners, Ian,Lloyd-Jones, Guy C.,Weller, Andrew S.. "Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]+ catalyst". supporting information. p. 9078 - 9093. Retrieved 2014/07/08.