2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester

Base Information

• Chemical Name: 2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester
• CAS No.: 51117-47-6
• Molecular Formula: C₁₉H₁₃N₃O₉S
• Molecular Weight: 459.393
• Mol file: 51117-47-6.mol

Synonyms:2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester

Chemical Property of 2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester

There total 1 articles about 2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver 2,4,6-trinitrobenzenesulfonate (18681-53-3) + diphenylchloromethane (90-99-3) → 2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester (51117-47-6)

Guidance literature:

In dichloromethane; Ambient temperature;

DOI:10.1021/jo00144a034

Reference yield: 67.8%

2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester (51117-47-6) + phenylacetylene (536-74-3) → 1,3,3-triphenylpropan-1-one (606-86-0) + 1,3,3-triphenylpropyne (5467-43-6) + 2,4,6-Trinitro-benzenesulfonic acid 1-phenyl-vinyl ester (82951-43-7) + 2,4,6-Trinitro-benzenesulfonic acid (E)-1,3,3-triphenyl-propenyl ester (82963-10-8) + acetophenone (98-86-2)

Guidance literature:

In dichloromethane; for 15h; Product distribution; Mechanism; Heating; var. molar ratio od reactants in the presence of cis-stilbene or 1-hexyne or cyclohexene oxide; other diphenylmethylsulfonic esters;

DOI:10.1021/jo00144a034

Reference yield: 28.5%

2,4,6-Trinitro-benzenesulfonic acid benzhydryl ester (51117-47-6) + phenylacetylene (536-74-3) → 1,3,3-triphenylpropan-1-one (606-86-0) + 1,3,3-triphenylpropyne (5467-43-6) + 2,4,6-Trinitro-benzenesulfonic acid (E)-1,3,3-triphenyl-propenyl ester (82963-10-8)

Guidance literature:

In dichloromethane; for 15h; Heating;

DOI:10.1021/jo00144a034

upstream raw materials:

silver 2,4,6-trinitrobenzenesulfonate

diphenylchloromethane

Downstream raw materials:

1,3,3-triphenylpropan-1-one

1,3,3-triphenylpropyne

2,4,6-Trinitro-benzenesulfonic acid 1-phenyl-vinyl ester

2,4,6-Trinitro-benzenesulfonic acid (E)-1,3,3-triphenyl-propenyl ester

Refernces